NIST X-ray Photoelectron Spectroscopy Database

NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

Details Summary:

Tab Page Summary

General:

Element:

Formula:

Rh₄(CO)₁₂/C

XPS Formula:

oxygens in bridging carbonyl ligands

Name:

tetra-mu-carbonyl-nonacarbonyl tetrahedro-tetrarhodium/carbon

CAS Registry No:

19584-30-6

Class:

carbonyl ligand, catalyst, cluster, organometallic

Citation:

Author Name(s):

Apai G., Frederick B.G.

Journal:

Langmuir 3, 395

DOI:

Pub Year:

1987

book All Records in this Publication

Data Processing:

Photoelectron Line

532.70

Background Subtraction Method:

Other

Peak Location Method:

Gaussian

Full Width at Half-maximum Intensity (eV):

1.5

Gaussian Width (eV):

Lorentzian Width (eV):

Measurement:

Use of X-ray Monochromator:

Anode Material:

X-ray Energy:

Overall Energy Resolution (eV):

Calibration:

Other, C1s=284.44

Charge Reference:

Internal hydrocarbon

Energy Scale Evaluation:

Reliable, with one-point correction of energy scale

Comment:

1-3 ML Rh6(CO)12/C. C1s energy of the substrate carbon atoms (Eb = 284.44 eV) was used for charge reference.

Specimen:

Method of Determining Specimen Composition:

Method of Determining Specimen Crystallinity:

Specimen Temperature (K):

193