NIST X-ray Photoelectron Spectroscopy Database

NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

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Ru

[Ru(NH₃)₅(NCCH₃)](PF₆)₂

[Ru*(NH₃)₅(NCCH₃)](PF₆)₂

pentaammine(acetonitrile)ruthenium bis(hexafluorophosphate))

CAS Registry No:

(iso)cyanide, ammonia-aminyl ligand, fluoride, nitrogen

Author Name(s):

Shepherd R.E., Proctor A., Henderson W.W., Myser T.K.

Inorg. Chem. 26, 2440

Pub Year:

1987

book All Records in this Publication

Photoelectron Line

Line Designation:

3d_5/2

Binding Energy (eV):

280.50

Energy Uncertainty:

0.2

Background Subtraction Method:

other

Peak Location Method:

other type of curve fit

Full Width at Half-maximum Intensity (eV):

Gaussian Width (eV):

Lorentzian Width (eV):

Use of X-ray Monochromator:

Yes

Anode Material:

Al

X-ray Energy:

Overall Energy Resolution (eV):

Calibration:

Au4f7 = 84.00

Charge Reference:

Internal hydrocarbon

Energy Scale Evaluation:

Reliable, with one-point correction of energy scale

Comment:

The linearity of the spectrometer over 0-1000 eV was 0.1 eV. The binding energy of adventitious carbon on gold foil was 284.6 eV. Doublet separation for the Ru3d was 4.1 eV. Branching ratio was 0.69

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