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NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

Details Summary:
Summary Page
Tab Page Summary

General:
Element:
Au
Formula:
[Au(CH2)2P(C6H5)2]2Br2
XPS Formula:
gold(I) atoms
Name:
bis(mu-dimethylenediphenylphosphino)-1,1-dibromodigold
CAS Registry No:
Class:
bromide, organometallic, phenyl benzene

Citation:
Author Name(s):
Raptis R.G., Porter L.C., Emrich R.J., Murray H.H., Fackler J.P., Jr.
Journal:
Inorg. Chem. 29, 4408
DOI:
Pub Year:
1990

Data Processing:
Data Type:
Photoelectron Line
Line Designation:
4f7/2
Binding Energy (eV)
84.25
Energy Uncertainty:
Background Subtraction Method:
other
Peak Location Method:
other type of curve fit
Full Width at Half-maximum Intensity (eV):
Gaussian Width (eV):
Lorentzian Width (eV):

Measurement:
Use of X-ray Monochromator:
No
Anode Material:
Mg
X-ray Energy:
Overall Energy Resolution (eV):
Calibration:
Au4f7 = 84.00
Charge Reference:
Internal hydrocarbon
Energy Scale Evaluation:
Reliable, with one-point correction of energy scale
Comment:
Mixed-valence, symmetrically bridged Au(I)/Au(III) complex. The Au4f peaks were analyzed by applying the maximum entropy method of spectral estimation to deconvolve this spectral region.

Specimen:
Specimen:
Method of Determining Specimen Composition:
Method of Determining Specimen Crystallinity:
Specimen Temperature (K):
77
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