NIST X-ray Photoelectron Spectroscopy Database

NIST X-ray Photoelectron Spectroscopy Database (SRD 20), Version 5.0

Details Summary:

Tab Page Summary

General:

Element:

Formula:

[P(C₆H₅)₃CNPt(AuP(C₆H₅)₃)₆]NO₃

Name:

cyano(triphenylphosphine)hexakis(triphenylphosphinegold)platinum nitrate

CAS Registry No:

Class:

catalyst, cluster, cyanide, nitrate, organometallic, phenyl benzene

Citation:

Author Name(s):

Shul'ga Y.M., Bulatov A.V., Gould R.A.T., Konze W.V., Pignolet L.H.

Journal:

Inorg. Chem. 31, 4704

DOI:

Pub Year:

1992

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Data Processing:

Photoelectron Line

4f_7/2

84.50

Background Subtraction Method:

Peak Location Method:

data

Full Width at Half-maximum Intensity (eV):

1.60

Gaussian Width (eV):

Lorentzian Width (eV):

Measurement:

Use of X-ray Monochromator:

Anode Material:

X-ray Energy:

Overall Energy Resolution (eV):

Calibration:

Au4f7 = 84.00

Charge Reference:

Internal hydrocarbon

Energy Scale Evaluation:

Reliable, with two-point correction of energy scale

Comment:

The full-width at the half-maximum of the Au 4f7/2 peak from metallic gold was 1.16 eV. The Pt4f7/2/Au4f7/2 intensity ratio was 0.24.

Specimen:

Method of Determining Specimen Composition:

Method of Determining Specimen Crystallinity:

Specimen Temperature (K):

300