Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1-Dichloroethene (1,1-dichloroethylene) with Water.
Components:
(1) 1,1-Dichloroethene (1,1-dichloroethylene); C2H2Cl2; [75-35-4]
NIST Chemistry WebBook
for detail
(2) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
DeLassus, P.T.; Schmidt, D.D., J. Chem. Eng. Data 26, 274 (1981).
Variables:
Temperature = 288 K - 364 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* Mass Fraction w
1
10
4
* Mole Fraction x
1
(compiler)
10
2
* w
1
/M
1
(compiler) [mol g**-1]
15
0.24
4.47
2.47 x 10
-3
17
0.255
4.75
2.63 x 10
-3
20.5
0.25
4.65
2.58 x 10
-3
25
0.225
4.19
2.32 x 10
-3
28.5
0.24
4.47
2.47 x 10
-3
29.5
0.255
4.75
2.63 x 10
-3
38.5
0.22
4.09
2.27 x 10
-3
45
0.21
3.91
2.17 x 10
-3
51
0.23
4.28
2.37 x 10
-3
55
0.21
3.91
2.17 x 10
-3
60
0.24
4.47
2.47 x 10
-3
65
0.225
4.19
2.32 x 10
-3
71
0.295
5.49
3.04 x 10
-3
74.5
0.25
4.65
2.58 x 10
-3
81
0.295
5.49
3.04 x 10
-3
85.5
0.37
6.90
3.82 x 10
-3
90.5
0.35
6.52
3.61 x 10
-3
Method/Apparatus/Procedure:
Approximately 60 cm
3
each of 1,1-dichloroethene and water was placed in a steel bomb and immersed in a thermostat bath. After 6-24 hours mechanical shaking, samples were taken from the water phase using a syringe and injected into a measured aliquot of dimethylacetamide. The solutions were then analyzed using a gas chromatograph technique. Three or more samples were taken at each temperature.
Source and Purity of Materials:
(1) Source not given, stabilized with monomethyl ether and hydroquinone.
(2) Distilled.
Estimated Errors:
Solubility: ± 5 %.
Temperature: ± 0.5 K (compiler).