IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,1,1-Trichloroethane with Water.
Components:
   (1) 1,1,1-Trichloroethane; C2H3Cl3; [71-55-6]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
Original Measurements:
   Lincoff, A.H.; Gossett, J.M., in Gas Transfer at Water Surfaces by Brutsaert, W. and Jirka, G.H., Eds., D. Reidel Publ. Co., Dordrecht, 1984, p. 17-25.

 Variables:
   Temperature = 293 K

 Prepared By:
   A. L. Horvath

 Experimental Remarks:
   EPICS Method: loge H=10.21-4262/(T/K)
Batch air stripping method: loge H=9.975-4186/(T/K).

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CHenry's law constant [(dimensionless)]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)Comment(s)
201.32 x 10-20.13131.775EPICS Method
201.34 x 10-20.12931.748Batch Air Stripping
 Method/Apparatus/Procedure:
   Henry's law constants were measured by EPICS and Batch Air Stripping Methods. The Equilibrium Partitioning in the Closed Systems technique compares the GC peak heights upon direct injection of headspace samples. In the Batch Air Stripping Method,  equal volume samples were placed in serum bottles and the equilibrated headspaces contained concentrations proportional to original concentrations in the aqueous samples. Full equilibrium was achieved in a few hours.

 Source and Purity of Materials:
   (1) Source and purity not given.
   (2) Distilled.

 Estimated Errors:
   Solubility: ± 5% - 10 %.
   Temperature: ± 0.1 K.