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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1-Dichloroethane with Water.
Components:
(1) 1,1-Dichloroethane; C2H4Cl2; [75-34-3]
NIST Chemistry WebBook
for detail
(2) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Gross, P.M., J. Am. Chem. Soc. 1929, 51, 2362-6.
Variables:
Temperature = 298 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* g
1
/g
2
10
2
* Mass Fraction w
1
(compiler)
10
4
* Mole Fraction x
1
(compiler)
25
0.506
0.503
9.19
Method/Apparatus/Procedure:
A weighted amount of 1,1-dichloroethane was mixed with 1000 g water in a bottle and immersed in a waterbath thermostat. The bottle was placed on a shaker and shaken until no more droplets of the liquid remained undissolved. The concentration of 1,1-dichloroethane in water was determined using a Zeiss water interferometer. One or more samples were syphoned out for the determination of the solubility. The German translation of the article is also published.
1
Source and Purity of Materials:
(1) Commercial reagent, fractionally distilled before use.
(2) Distilled.
Estimated Errors:
Solubility: ± 2.0 %.
Temperature: ± 0.01 K.
References:
1
P. M. Gross, Z. Phys. Chem.
6B
, 215 (1929).