IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,3-Dichloro-1-propene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,3-Dichloro-1-propene; C3H4Cl2; [542-75-6]  NIST Chemistry WebBook for detail
Original Measurements:
   Warner, H.P.; Cohen, J.M.; Ireland, J.C., Determination of Henry's Law Constants of Selected Priority Pollutants, U. S. EPA Technical Report, PB87-212684, Cincinnati, OH., July 1987.

 Variables:
   Temperature = 298 K

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°CHenry's law constant [m**3 atm mol**-1]102 * Mass Fraction w1 (compiler) 104 * Mole Fraction x1 (compiler)
24.853.55 x 10-30.10321.676
 Method/Apparatus/Procedure:
   The original method and apparatus for the determination of Henry's law constants are described elsewhere.1 The general procedure was to add an excess quantity of 1,3-dichloro-1-propene to distilled deionized water,  place the sample in a thermostat bath, and provide place the sample in a thermostat bath, and provide overnight mixing. A portion of this solution was returned to the stripping vessel. 1,3-Dichloro-1-propene was stripped  isothermally from the solution at a know gas flow rate. The Henry’s law constant was calculated from a log of the concentration versus time plot. The experimental data values are averages of two or more replicates.

 Source and Purity of Materials:
   (1) Purest quality available, used without further purification. Stated purity was >99%.
   (2) Distilled deionized.

 Estimated Errors:
   Solubility: ± 6 % std. dev.
   Temperature: ± 0.05 K.

 References:
   1 D. Mackay, W. -Y. Shiu, and R. D. Sutherland, Environ. Sci. Technol. 13, 333 (1979).