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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,1,2,3,3,3-Hexachloro-1-propene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,1,2,3,3,3-Hexachloro-1-propene; C3Cl6; [1888-71-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Simonov, V.D., et al., Dokl. Neftekim. Sekt. Bashkir. Respub. Pravl. Vses. Khim. Obshchest. 1971, 346-51.
Variables:
Temperature = 288 K - 299 K
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
5
* Mass Fraction w
1
10
4
* Mole Fraction x
1
(compiler)
Comment(s)
14.5
3.35
4.624
Alekseev
16
3.93
5.424
Alekseev
20
4.07
5.619
Alekseev
26
5.25
7.244
Alekseev
14.5
3.32
4.582
Fischer
16
3.89
5.369
Fischer
20
-
-
Fischer
26
5.20
7.175
Fischer
14.5
3.30
4.555
Spectroscopy
16
3.85
5.313
Spectroscopy
20
4.24
5.865
Spectroscopy
26
5.30
7.313
Spectroscopy
Method/Apparatus/Procedure:
The determination of the solubility of water in 1,1,2,3,3,3-hexachloro-1-propene was based on the infrared spectroscopic method. A UR-20 spectrophotometer was used with 2-cm cuvettes and the windows made of KBr. The spectra were recorded at 3600-810 cm
-1
, and the absorbance at 3702 cm-1 was found by the baseline method. Standard mixtures of 1,1,2,3,3,3-hexachloro-1-propene and water were used for the calibration graphs. The results obtained were compared with the measurements made by the methods of cloud point
1
and a Karl Fischer titration.
Source and Purity of Materials:
(1) Distilled.
(2) Synthesized by the authors, distilled, washed with HClSO
3
and water and again distilled. Finally dried with CaCl
2
and P
2
O
5
.
Estimated Errors:
Solubility: Not specified.
Temperature: ± 0.5 K.
References:
1
V. F. Alekseev, Wied. Ann. 28, 305 (1886).