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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Carbon dioxide with Copolymer of ethylene-vinyl-acetone (CEVA) and Chlorosulphonated polyethylene Hypalon-48 (CPE)
Components:
(1) Carbon dioxide; CO2; [124-38-9]
NIST Chemistry WebBook
for detail
(2) Chlorosulphonated polyethylene Hypalon-48 (CPE); ; []
NIST Chemistry WebBook
for detail
(3) Copolymer of ethylene-vinyl-acetate (CEVA); ; [24937-78-8]
NIST Chemistry WebBook
for detail
Original Measurements:
J.A. Barrie and, W.D. Webb, Polymer 30, 327-332 (1989).
Variables:
Temperature = 303 K - 323 K
Pressure = 303 K - 323 K
Concentration = CEVA conc. in blends, wt %: 0-100
Prepared By:
Yu. P. Yampol'skii
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
Solubility in miscible blends of CEVA and CPE obeys Henry's law.
Solubility coefficients
S
10
2
/(cm
3
(STP)/cm
3
cm Hg) of CO
2
in the blends.
T/K
Gas Temperature (T
gas
)
Pressure [g/cm
3
]
Keunen coefficient, S
Remark(s)
303
257
0.98
2.00
100 [CEVA, wt%]
303
257
0.98
1.87
90
303
257
0.98
1.81
80
303
257
0.98
1.71
70
303
257
0.98
1.56
60
303
257
0.98
1.52
50
303
257
0.98
1.42
40
303
257
0.98
1.33
30
303
257
0.98
1.27
20
303
293
1.27
1.10
0
313
257
0.98
1.73
100
313
257
0.98
1.59
90
313
257
0.98
1.57
80
313
257
0.98
1.44
70
313
257
0.98
1.35
60
313
257
0.98
1.32
50
313
257
0.98
1.22
40
313
257
0.98
1.15
30
313
257
0.98
1.10
20
313
293
1.27
0.96
0
323
257
0.98
1.48
100
323
257
0.98
1.38
90
323
257
0.98
1.37
80
323
257
0.98
1.26
70
323
257
0.98
1.18
60
323
257
0.98
1.17
50
323
257
0.98
1.08
40
323
257
0.98
1.00
30
323
257
0.98
0.98
20
323
293
1.27
0.85
0
Method/Apparatus/Procedure:
Sorption measurements were performed using a vacuum electronic microbalance (Sartorius Instruments).
Source and Purity of Materials:
CEVA containing 45 wt.% of vinyl acetate with
M
w
= 37,700 from Bayer Co and CPE (Hypalon 48) from DuPont, UK obtained by sulphochlorination of PE having
M
n
= 23,900 (Cl content 44 wt.%) were studied. A small but not specified content of SO
2
Cl groups in CPE is possible. Both polymers were shown by X-ray diffraction to be amorphous. Some phase separation is reported for the blends with CEVA content lower than 50 % (DSC data).
Estimated Errors: