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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Nitromethane with 1-Hexanol
Components:
(1) Nitromethane; CH3NO2; [75-52-5]
NIST Chemistry WebBook
for detail
(2) 1-Hexanol; C6H14O; [111-27-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Zhuravleva, I.K.; Zhuravlev, E.F.; Rudakova, N.A., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 18, 333 (1975); Deposited Doc., VINITI 1587 (1974).
Variables:
Temperature = 283 K to 309 K
Prepared By:
V. P. Sazonov
Experimental Data:
(Notes on the Nomenclature)
Mutual solubility of nitromethane and 1-hexanol
t/°C
T/K
10
2
* Mass Fraction w
1
Mole Fraction x
1
(compiler)
Comment(s)
9.5
282.7
11.0
0.171
Alcohol-rich phase
9.5
282.7
-
-
Nitromethane-rich phase
15.5
288.7
13.5
0.207
Alcohol-rich phase
15.5
288.7
-
-
Nitromethane-rich phase
16.0
289.2
-
-
Alcohol-rich phase
16.0
289.2
89.3
0.933
Nitromethane-rich phase
20.0
293.2
16.6
0.250
Alcohol-rich phase
20.0
293.2
-
-
Nitromethane-rich phase
24.0
297.2
19.3
0.286
Alcohol-rich phase
24.0
297.2
-
-
Nitromethane-rich phase
26.5
299.7
21.3
0.312
Alcohol-rich phase
26.5
299.7
-
-
Nitromethane-rich phase
29.0
302.2
24.3
0.350
Alcohol-rich phase
29.0
302.2
-
-
Nitromethane-rich phase
30.0
303.2
-
-
Alcohol-rich phase
30.0
303.2
79.9
0.869
Nitromethane-rich phase
30.5
303.7
26.6
0.378
Alcohol-rich phase
30.5
303.7
-
-
Nitromethane-rich phase
32.5
305.7
30.5
0.424
Alcohol-rich phase
32.5
305.7
-
-
Nitromethane-rich phase
33.0
306.2
32.5
0.446
Alcohol-rich phase
33.0
306.2
-
-
Nitromethane-rich phase
34.0
307.2
36.0
0.485
Alcohol-rich phase
34.0
307.2
-
-
Nitromethane-rich phase
35.0
308.2
38.5
0.512
Alcohol-rich phase
35.0
308.2
-
-
Nitromethane-rich phase
35.0
308.2
41.4
0.542
Alcohol-rich phase
35.0
308.2
-
-
Nitromethane-rich phase
35.0
308.2
45.2
0.580
Alcohol-rich phase
35.0
308.2
-
-
Nitromethane-rich phase
35.0
308.2
49.4
0.620
Alcohol-rich phase
35.0
308.2
-
-
Nitromethane-rich phase
36.0
309.2
-
-
Alcohol-rich phase
36.0
309.2
69.1
0.789
Nitromethane-rich phase
36.0
309.2
-
-
Alcohol-rich phase
36.0
309.2
59.9
0.714
Nitromethane-rich phase
35.6
308.8
52.5
0.649
Alcohol-rich phase
35.6
308.8
52.5
0.649 (UCST)
Nitromethane-rich phase
Method/Apparatus/Procedure:
The synthetic method
1
was used. No further details were reported.
Source and Purity of Materials:
(1) Source not specified; purity not specified; distilled; b.p. = 101.3 °C,
n
(20 °C,D) = 1.3820,
d
(20 °C) = 1132.0 g·L
−1
.
(2) Source not specified; purity not specified; distilled; b.p. = 157.2 °C,
n
(20 °C,D) = 1.4190,
d
(20 °C) = 818.6 g·L
−1
.
Estimated Errors:
Solubility: Not reported.
Temperature: Not reported.
Pressure: Not reported.
References:
1
V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).