IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Nitromethane with 1-Hexanol

Components:
   (1) Nitromethane; CH3NO2; [75-52-5]  NIST Chemistry WebBook for detail
   (2) 1-Hexanol; C6H14O; [111-27-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Zhuravleva, I.K.; Zhuravlev, E.F.; Rudakova, N.A., Zh. Obshch. Khim. 46, 2178-86 (1976).

Variables:
   Temperature = 289 K to 308 K

Prepared By:
   V. P. Sazonov

Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitromethane and 1-hexanol
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
15.5288.7--Alcohol-rich phase
15.5288.790.00.938Nitromethane-rich phase
24.5297.719.40.287Alcohol-rich phase
24.5297.7--Nitromethane-rich phase
30.0303.2--Alcohol-rich phase
30.0303.279.30.865Nitromethane-rich phase
31.0304.227.70.391Alcohol-rich phase
31.0304.2--Nitromethane-rich phase
34.0307.239.10.518Alcohol-rich phase
34.0307.270.30.799Nitromethane-rich phase
35.0308.249.00.617Alcohol-rich phase
35.0308.260.10.716Nitromethane-rich phase
35.0308.252.50.649Alcohol-rich phase
35.0308.252.50.649 (UCST)Nitromethane-rich phase
Method/Apparatus/Procedure:
   The synthetic method1 was used. No further details were reported.

Source and Purity of Materials:
   (1) Source not specified; purity not specified; distilled; n(20 °C, D) = 1.3820, d(20 °C) = 1132.0 g·L−1.
   (2) Source not specified; purity not specified; distilled; n(20 °C, D) = 1.4135, d(20°C) = 818.6 g·L−1.

Estimated Errors:
   Solubility: Not reported.
   Temperature: Not reported.
   Pressure: Not reported.

References:
   1 V. F. Alekseev, Zh. Russ. Fiz.-Khim. O-va 8, 249 (1876).