IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Nitroethane with 1-Dodecanol
Components:
   (1) 1-Dodecanol; C12H26O; [112-53-8]  NIST Chemistry WebBook for detail
   (2) Nitroethane; C2H5NO2; [79-24-3]  NIST Chemistry WebBook for detail
Original Measurements:
   Francis, A.W., J. Phys. Chem. 60, 20-7 (1956).

 Variables:
   Temperature = 287 K to 300 K

 Prepared By:
   V. P. Sazonov and N. I. Lisov

 Experimental Data:   (Notes on the Nomenclature)
  
Mutual solubility of nitroethane (1) and 1-dodecanol (2)
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
14.0287.2--alcohol-rich phase
16.0289.2--alcohol-rich phase
20.0293.223.00.426alcohol-rich phase
24.0297.230.00.516alcohol-rich phase
26.5299.755.0 0.752 alcohol-rich phase
Mutual solubility of nitroethane (1) and 1-dodecanol (2)
t/°CT/K102 * Mass Fraction w1Mole Fraction x1 (compiler)Comment(s)
14.0287.292.00.966nitroethane-rich phase
16.0289.290.00.957nitroethane-rich phase
20.0293.284.00.929nitroethane-rich phase
24.0297.275.00.882nitroethane-rich phase
26.5299.755.0 0.752 (UCST)nitroethane-rich phase
 Method/Apparatus/Procedure:
   The observations were made after vigorously shaking glass stoppered graduated tubes of about 15 mL capacity immersed in water-baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding small amounts of cooler or warmer water occasionally as required.

 Source and Purity of Materials:
   (1) Eastman Kodak Co.; distilled with 30 cm column with reflux; b. p. = 114 °C-115 °C; n(20 °C,D) = 1.3920, p(20°C) = 1046.9 g·L-1.
   (2) Source not specified; purified by crystallization; m. p. = 22.7 °C; n(24 °C,D) = 1.4410 p(24°C) = 832.0 g·L-1.

 Estimated Errors:
   Solubility: Not specified.
   Temperature: Not specified.