IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,4-Diiodobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,4-Diiodobenzene; C6H4I2; [624-38-4]  NIST Chemistry WebBook for detail
Original Measurements:
   Andrews, L.J.; Keefer, R.M., J. Am. Chem. Soc. 1950, 72(7), 3113-6.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. Vesala

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * g1/V2 [g dm**-3]106 * Concentration c1 [mol dm**-3]Concent. c1 Note108 * Mole Fraction x1x1 Note
251.44.24b7.67b
 Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.

 Method/Apparatus/Procedure:
   The saturation process was done in sealed Erlenmeyer flasks. The time used for the equilibration was 20 hours. Measured volumes of the saturated solution were then extracted using measured volumes of hexane to remove the aromatic compound from the aqueous layer. The solute concentration was measured spectrophotometrically (1).

 Source and Purity of Materials:
   (1) Commercial product (Eastman Kodak Co.), recrystallized twice from ethanol, reporting melting point 360-361 K.
   (2) Source and purity not specified.

 Estimated Errors:
   Solubility: >10% (compiler).
   Temperature: ± 0.2 K.

 References:
   1Andrews, L. J.; Keefer, R. M. J. Am. Chem. Soc. 1949, 71(11), 3644-7.