IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Bromobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Bromobenzene; C6H5Br; [108-86-1]  NIST Chemistry WebBook for detail
Original Measurements:
   Bell, R.P., J. Chem. Soc. 1932, 2905-11.

 Variables:
   Temperature = Temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * g1/V2 [g dm**-3]102 * Concentration c1 [mol dm**-3]Concent. c1 Note103 * Mole Fraction x1x1 Note
152.491.382b1.443c
203.061.698b1.781c
253.742.075b2.186c
 Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   About 1 to 5 ratio solute/solvent mixtures were rotated in a thermostat bath for 12 hrs. After equilibrium was established, samples were taken and filtered through cottonwool. The determination of the water content was based on the reaction with o-naphthoxydichlorophosphine. The evolvedHCI was absorbed in water and titrated with NaOH solution (1). Successive (2-$0 determinations were carried out with the solvent.

 Source and Purity of Materials:
   (1) Distilled (compiler).
   (2) Merck reagent, analytical grade, redistilled before use.

 Estimated Errors:
   Solubility: ± 2.6%.
   Temperature: ± 0.02 K.

 References:
   1Bell, R. P. J. Chem. Soc. 1932, Part II, 2903-5.