IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Bromobenzene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Bromobenzene; C6H5Br; [108-86-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Hine, J.; Haworth, H.W.; Ramsay, O.B., J. Am. Chem. Soc. 1963, 85(10), 1473-6.

Variables:
   Temperature = One temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * g1/V2 [g dm**-3]103 * Concentration c1 [mol dm**-3]Concent. c1 Note105 * Mole Fraction x1x1 Note
354.5852.92b5.294c
Notes:
   a  Calculated by F. W. Getzen.
   b  Reported.
   c  Calculated by compiler.

Method/Apparatus/Procedure:
   An excess of bromobenzene was combined with 4 ml of water in an ampoule and sealed. The sealed ampoule was then rotated in a water bath for a week. The bromobenzene solubility was determined by ultraviolet spectrophotometric measurements using a Beckman DU spectrophotometer.

Source and Purity of Materials:
   (1) Eastman Kodak Co., redistilled before use.
   (2) Not specified.

Estimated Errors:
   Solubility: ±2% S.D.
   Temperature: ±0.1 K.