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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Bromobenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Bromobenzene; C6H5Br; [108-86-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Hine, J.; Haworth, H.W.; Ramsay, O.B., J. Am. Chem. Soc. 1963, 85(10), 1473-6.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
1
* g
1
/V
2
[g dm**-3]
10
3
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
5
* Mole Fraction x
1
x
1
Note
35
4.585
2.92
b
5.294
c
Notes:
a
Calculated by F. W. Getzen.
b
Reported.
c
Calculated by compiler.
Method/Apparatus/Procedure:
An excess of bromobenzene was combined with 4 ml of water in an ampoule and sealed. The sealed ampoule was then rotated in a water bath for a week. The bromobenzene solubility was determined by ultraviolet spectrophotometric measurements using a Beckman DU spectrophotometer.
Source and Purity of Materials:
(1) Eastman Kodak Co., redistilled before use.
(2) Not specified.
Estimated Errors:
Solubility: ±2% S.D.
Temperature: ±0.1 K.