IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Bromobenzene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Bromobenzene; C6H5Br; [108-86-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Jones, J.R.; Monk, C.B., J. Chem. Soc. 1963, 2633-5.

Variables:
   Temperature = Temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)


t/°C	Concentration c₁ [mol dm**-3]	Concent. c₁ Note	Mole Fraction x₁	x₁ Note
25	.0227	b	0.0239	c
30	.0260	b	0.0275	c
35	.0292	b	0.0310	c

Notes:
   ^a  Reported.
   ^b  Calculated by F. W. Getzen.
   ^c  Calculated by compiler.

Method/Apparatus/Procedure:
   Tritiated water was shaken with bromobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.

Source and Purity of Materials:
   (1) Tritiated.
   (2) Source not known, laboratory grade, dried over CaCI₂ and fractionally distilled before use.

Estimated Errors:
   Solubility: ±5%.
   Temperature: ±0.5 K (compiler).