IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Chlorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail
Original Measurements:
   Gross, P.M.; Saylor, J.H., J. Am. Chem. Soc. 1931, 53, 1744-51.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * Molality mol1/kgmol1/kg Note101 * g1/kgg1/kg Note105 * Mole Fraction x1x1 Note
304.333b4.88a7.810c
 Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   An excess of chlorobenzene in 500 g water was shaken for 12 hours in a thermostat bath. Samples were then withdrawn and read against water as a reference using an interferometer made by Zeiss (1). A detailed description of the complete procedure has been described in a Ph.D. dissertation (2).

 Source and Purity of Materials:
   (1) Eastman Kodak Co., was purified by fractional distillation before use.
   (2) Distilled.

 Estimated Errors:
   Solubility: ±1.0%.
   Temperature: ±0.02 K.

 References:
   1Gross, P. M. J. Am. Chem. Soc. 1929, 51(8). 2362-6.
   2 Saylor, J. H., Ph.D. Thesis, Duke University, Durham, 1930.