IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Chlorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail
Original Measurements:
   Hutchinson, C.A.; Lyon, A.M., Columbia University Report A-745, July 1, 1943.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * Molality mol1/kgmol1/kg Note101 * g1/kgg1/kg Note103 * Mole Fraction x1x1 Note
252.50b4.504a2.807c
 Notes:
   a  Calculated by F. W. Getzen.
   b  Reported.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   Mixtures of 1 to 15 volume ratios of solute to solvent were introduced into an equilibration flask and placed in water thermostat bath. The assembly was shaken mechanically for about 90 minutes at constant temperature. The amount of water in the organic phase was determined by a modified Karl Fischer titration. The determinations were done in triplicate. The experimental procedure was taken from a secondary source (1). The original report is no longer available.

 Source and Purity of Materials:
   (1) Distilled.
   (2) Source is not known, purified and dried before use.

 Estimated Errors:
   Solubility: ±1%.
   Temperature: ±0.05 K.

 References:
   1Eidinoff, M. L. In "Production of Heavy Water", National Nuclear Energy Series Division III-Vol.4F, Murphy, G. M.; Urey, H. C.; Kirshenbaum, I., Eds.; McGraw-Hill: New York, 1955; Part II, Chapter 7, pp 129-44.