IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Chlorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail
Original Measurements:
   Andrews, L.J.; Keefer, R.M., J. Am. Chem. Soc. 1950, 72(7), 3113-6.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * g1/V2 [g dm**-3]103 * Concentration c1 [mol dm**-3]Concent. c1 Note105 * Mole Fraction x1x1 Note
255.04.44b8.03c
 Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   Water was saturated with chlorobenzene in a glass stoppered Erlenmeyer flask by rotating the flask in a constant temperature bath for 20 hours. The saturated solution was extracted with n-hexane for analysis. The optical density of the extract was measured against a n-hexane standard using a Beckman spectrophotometer (1).

 Source and Purity of Materials:
   (1) Eastman Kodak Co., commercial reagent, b.p. 131.9-132°C, fractionated before use.
   (2) Not specified.

 Estimated Errors:
   Solubility: ±10% (compiler).
   Temperature: ±0.1 K (compiler).

 References:
   1Andrews, L. J.; Keefer, R. M. J. Am. Chem. Soc. 1949, 71(11), 3644-7.