IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

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 Solubility System: Chlorobenzene with Water

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Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Jones, J.R.; Monk, C.B., J. Chem. Soc. 1963, 2633-5.

Variables:
   Temperature = Temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  

t/°C	101 * V1/V2 [ml/dm**3]	102 * Concentration c1 [mol dm**-3]	Concent. c1 Note	103 * Mole Fraction x1	x1 Note
25	3.4 (a)	1.88	b	1.92	c
30	3.95 (a)	2.182	b	2.239	c
35	4.6 (a)	2.54	b	2.62	c

Notes:
   ^a  Reported.
   ^b  Calculated by F. W. Getzen.
   ^c  Calculated by compiler.

Method/Apparatus/Procedure:
   Tritiated water was shaken with bromobenzene in 1:10 volume ratios for 4 hours in a flask in a water thermostat bath. The water content was determined by tritium assay. The count rates were determined using a typical liquid scintillator solution technique.

Source and Purity of Materials:
   (1) Tritiated.
   (2) Source not known, laboratory grade, dried over CaCI₂ and fractionally distilled before use.

Estimated Errors:
   Solubility: ±5%.
   Temperature: ±0.5 K. (compiler).

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Last updated: February 18, 2015 (Created: August 17, 2007)