IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

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 Solubility System: Chlorobenzene with Water

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Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Chey, W.; Calder, G.V., J. Chem. Eng. Data 1972, 17(2), 199-200.

Variables:
   Temperature = One temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  

t/°C	103 * Molality mol1/kg	mol1/kg Note	101 * g1/kg	105 * Mole Fraction x1	x1 Note
21	4.742	b	5.34	8.546	c

Notes:
   ^a  Reported.
   ^b  Calculated by F. W. Getzen.
   ^c  Calculated by compiler.

Method/Apparatus/Procedure:
   A 1 to 50 volume ratio solute/solvent mixture was stirred in a separatory funnel for 20 hr in a thermostat bath. Then, the solution was passed through a separation column of nonpolar resin. The solute was eluted with isopropyl ether. Traces of water were removed using molecular sieve pellets, and the sample was injected into a gas chromatograph fitted with a stainless steel column packed with Chromosorb having a liquid phase of Carbowax for analysis. The determination was done in duplicate.

Source and Purity of Materials:
   (1) Source not specified, Analytical Reagent grade.
   (2) Distilled.

Estimated Errors:
   Solubility: ±2%.
   Temperature: ±1 K.

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Last updated: February 18, 2015 (Created: August 17, 2007)