IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: Chlorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Chlorobenzene; C6H5Cl; [108-90-7]  NIST Chemistry WebBook for detail
Original Measurements:
   Kirchnerova, J.; Cave, G.C.B., Can. J. Chem. 1976, 54(24), 3909-16.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * g1/V2 [g dm**-3]102 * Concentration c1 [mol dm**-3]Concent. c1 Note103 * Mole Fraction x1x1 Note
255.2252.90b2.959c
 Notes:
   a  Calculated by F. W. Getzen.
   b  Reported.
   c  Calculated by compiler.

 Method/Apparatus/Procedure:
   A mixture of 50 ml chlorobenzene and 6 ml water in a bottle was submerged in a water thermostat bath for 2 days. The concentration of the water in the organic phase was determined by a conventional Karl Fischer dead stop back titration. Determinations were done in triplicate. A detailed description of the complex experimental procedure has been included in a Ph.D. dessertation (1).

 Source and Purity of Materials:
   (1) Distilled and deionized.
   (2) Fischer - B255, washed with cc. H2SO4 and K2CO3 solutions and distilled water. Dried over silica gel and fractionally distilled, purity: 99.8%.

 Estimated Errors:
   Solubility: ±1%.
   Temperature: ±0.1 K.

 References:
   1Kirchnerova, J., Ph.D. Dissertation, McGill University, Montreal, Quebec, 1974.