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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
2-Chlorophenol with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 2-Chlorophenol; C6H5ClO; [95-57-8]
NIST Chemistry WebBook
for detail
Original Measurements:
Banerjee, S.; Yalkowsky, S.H.; Valvani, S.C., Environ. Sci. Technol. 1980, 14, 1227-9.
Variables:
Temperature = One temperature
Prepared By:
A. Vesala
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
-1
* g
1
/V
2
[g dm**-3]
10
2
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
3
* Mole Fraction x
1
x
1
Note
25
1.135
8.83
b
1.611
a
Notes:
a
Calculated by F. W. Getzen.
b
Reported.
Method/Apparatus/Procedure:
The equilibrations were performed in sealed stainless steel centrifuge tubes with constant or intermittent shaking. The equilibration was generally complete within 1 week. The mixture was then centrifuged for 60 minutes after which aliquots of the solution were removed for analysis either by a pipet or a syringe. Liquid scintilliation counting with
14
C-labeled solute was employed in solubility determinations. The entire procedure was carried out at least twice and each analysis was also conducted in duplicate.
Source and Purity of Materials:
(1) Commercial reagent, the
14
C-labeled compound was purchased by NEN, the nonlabeled one by Aldrich.
(2) Distilled.
Estimated Errors:
Solubility: ±0.5% (std. deviation estimated by authors).
Temperature: ±0.2 K (equilibration) ±0.3 K (centrifugation);