IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 2-Chlorophenol with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 2-Chlorophenol; C6H5ClO; [95-57-8]  NIST Chemistry WebBook for detail

Original Measurements:
   Banerjee, S.; Yalkowsky, S.H.; Valvani, S.C., Environ. Sci. Technol. 1980, 14, 1227-9.

Variables:
   Temperature = One temperature

Prepared By:
   A. Vesala

Experimental Data:   (Notes on the Nomenclature)
  
t/°C10-1 * g1/V2 [g dm**-3]102 * Concentration c1 [mol dm**-3]Concent. c1 Note103 * Mole Fraction x1x1 Note
251.1358.83b1.611a
Notes:
   a  Calculated by F. W. Getzen.
   b  Reported.

Method/Apparatus/Procedure:
   The equilibrations were performed in sealed stainless steel centrifuge tubes with constant or intermittent shaking. The equilibration was generally complete within 1 week. The mixture was then centrifuged for 60 minutes after which aliquots of the solution were removed for analysis either by a pipet or a syringe. Liquid scintilliation counting with 14C-labeled solute was employed in solubility determinations. The entire procedure was carried out at least twice and each analysis was also conducted in duplicate.

Source and Purity of Materials:
   (1) Commercial reagent, the 14C-labeled compound was purchased by NEN, the nonlabeled one by Aldrich.
   (2) Distilled.

Estimated Errors:
   Solubility: ±0.5% (std. deviation estimated by authors).
   Temperature: ±0.2 K (equilibration) ±0.3 K (centrifugation);