IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,2,3,5-Tetrachlorobenzene with Water

   (1) 1,2,3,5-Tetrachlorobenzene; C6H2Cl4; [634-90-2]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Banerjee, S.; Yalkowsky, S.H.; Valvani, S.C., Environ. Sci. Technol. 1980, 14, 1227-9.

   Temperature = One temperature

Prepared By:
   A. Vesala

Experimental Data:   (Notes on the Nomenclature)
t/°C103 * g1/V2 [g dm**-3]105 * Concentration c1 [mol dm**-3]Concent. c1 Note107 * Mole Fraction x1x1 Note
   a  Calculated by F. W. Getzen.
   b  Reported.

   The equilibrium was performed in sealed stainless steel centrifuge tubes with constant or intermittent shaking. The equilibrium was generally complete within 1 week. The mixture was then centrifuged for 60 minutes after which aliquots of the solution were removed for analysis either by a pipet or syringe. Liquid scintillation counting with 14c-labeled solute was employed in the solubility determinations. The entire porcedure was carried out at least twice and each analysis was also conducted in duplicate.

Source and Purity of Materials:
   (1) Commercial reagent, the 14c-labeled compound was purchased by NEN, the nonlabeled by Aldrich.
   (2) Distilled water.

Estimated Errors:
   Solubility: ± 4.0% (std. deviation estimated by authors).
   Temperature: ± 0.2 K (equilibration) ±0.3 K (centrifugation)