IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Iodobenzene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Iodobenzene; C6H5I; [591-50-4]  NIST Chemistry WebBook for detail

Original Measurements:
   Jones, J.R.; Monk, C.B., J. Chem. Soc. 1963, 2633-5.

Variables:
   Temperature = Temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * V1/V2 [ml/dm**3]102 * Concentration c1 [mol dm**-3]Concent. c1 Note103 * Mole Fraction x1x1 Note
254.9 (a)2.71b3.03c
305.6 (a)3.09b3.47c
356.35 (a)3.502b3.940c
Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

Method/Apparatus/Procedure:
   Tritiated water was shaken with iodobenzene in 1:10 volume ratios for 4 hours in flasks placed in a water thermostat bath. The water content was determined by tritium assay of samples taken from the flasks. The count rates were determined using a typical liquid scintillator solution technique.

Source and Purity of Materials:
   (1) Tritiated.
   (2) Source not known, laboratory grade, dried over CaCI2 and fractionally distilled before use.

Estimated Errors:
   Solubility: ± 5%.
   Temperature: ± 0.5 K (compiler).