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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,2,4-Trichlorobenzene with Water
Components:
(1) 1,2,4-Trichlorobenzene; C6H3Cl3; [120-82-1]
NIST Chemistry WebBook
for detail
(2) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Yalkowsky, S.H.; Orr, R.J.; Valvani, S.C., Ind. Eng. Chem. Fundam. 1979, 18(4), 351-3.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* g
1
/V
2
[g dm**-3]
10
4
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
6
* Mole Fraction x
1
x
1
Note
25
3.466
1.91
b
3.451
a
Notes:
a
Calculated by compiler.
b
Reported.
Method/Apparatus/Procedure:
A small excess of 1, 2, 4,- trichlorobenzene in water was agitated at room temperature for about 24 hours and then filtered. The filtrate was diluted and assayed spectrophotometrically. The determination was carried out in duplicate.
Source and Purity of Materials:
(1) Aldrich commercial grade, used as received.
(2) Deionized.
Estimated Errors:
Solubility: ± 10%
Temperature: ± 1 K.