IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,2,4-Trichlorobenzene with Water

Components:
   (1) 1,2,4-Trichlorobenzene; C6H3Cl3; [120-82-1]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Chiou, C.T.; Schmedding, D.W.; Manes, M., Environ. Sci. Technol. 1982, 16(1), 4-10.

Variables:
   Temperature = One temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C102 * g1/V2 [g dm**-3]104 * Concentration c1 [mol dm**-3]Concent. c1 Note106 * Mole Fraction x1x1 Note
254.8812.69b4.861a
Notes:
   a  Calculated by compiler.
   b  Reported.

Method/Apparatus/Procedure:
   An excess of 1, 2, 4-trichlorobenzene was equilibrated with water in screwcapped bottles in a reciprocal shaker for 24 hours. After two days settling, samples were taken from the solution for analysis by gas chromatography. The Chromatograph was equipped with a Ni63 EC detector. Analyses were continued until a constant concentration was observed.

Source and Purity of Materials:
   (1) Not specified.
   (2) Distilled.

Estimated Errors:
   Solubility: ± 5% (compiler).
   Temperature: ± 0.5 K.

References:
   1Chiou, C. T. Hazard Assess. Chem. Current Dev. 1981, 1, 117-53.