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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1-Bromo-3-chlorobenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1-Bromo-3-chlorobenzene; C6H4BrCl; [108-37-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Yalkowsky, S.H.; Orr, R.J.; Valvani, S.C., Ind. Eng. Chem. Fundam. 1979, 18(4), 351-3.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
1
* g
1
/V
2
[g dm**-3]
10
4
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
5
* Mole Fraction x
1
x
1
Note
25
1.181
6.17
b
1.115
a
Notes:
a
Calculated by compiler.
b
Reported.
Method/Apparatus/Procedure:
A small excess of 1-bromo-3-chlorobenzene in water was agitated at room temperature for a period of about 24 hours and then filtered. The saturated filtrate solution was diluted and assayed spectrophotometrically. Two independent determinations were carried out.
Source and Purity of Materials:
(1) Aldrich commercial grade, used as received.
(2) Deionized.
Estimated Errors:
Solubility: ± 10%.
Temperature: ± 1K.