IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,3-Dibromobenzene with Water

   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,3-Dibromobenzene; C6H4Br2; [108-36-1]  NIST Chemistry WebBook for detail

Original Measurements:
   Hine, J.; Haworth, H.W.; Ramsay, O.B., J. Am. Chem. Soc. 1963, 85(10), 1473-6.

   Temperature = One temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
t/°C102 * g1/V2 [g dm**-3]104 * Concentration c1 [mol dm**-3]Concent. c1 Note106 * Mole Fraction x1x1 Note
   a  Calculated by F. W. Getzen.
   b  Reported.
   c  Calculated by compiler.

   An excess of 1,3-dibromobenzene was added to a 4 ml of water in an ampoule which was then sealed. The sealed ampoule was rotated in a constant temperature water bath for a week to establish saturation. The 1,3-dibromobenzene solubility was determined by ultraviolet spectrophotometric measurements using a Beckman DU spectrophotometer.

Source and Purity of Materials:
   (1) Eastman Kodak Co.; redistilled before use.
   (2) Not specified.

Estimated Errors:
   Solubility: ±5.6 % S.D.
   Temperature: ±0.1 K.