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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,3-Dibromobenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,3-Dibromobenzene; C6H4Br2; [108-36-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Hine, J.; Haworth, H.W.; Ramsay, O.B., J. Am. Chem. Soc. 1963, 85(10), 1473-6.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
2
* g
1
/V
2
[g dm**-3]
10
4
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
6
* Mole Fraction x
1
x
1
Note
30
6.747
2.86
b
5.184
c
Notes:
a
Calculated by F. W. Getzen.
b
Reported.
c
Calculated by compiler.
Method/Apparatus/Procedure:
An excess of 1,3-dibromobenzene was added to a 4 ml of water in an ampoule which was then sealed. The sealed ampoule was rotated in a constant temperature water bath for a week to establish saturation. The 1,3-dibromobenzene solubility was determined by ultraviolet spectrophotometric measurements using a Beckman DU spectrophotometer.
Source and Purity of Materials:
(1) Eastman Kodak Co.; redistilled before use.
(2) Not specified.
Estimated Errors:
Solubility: ±5.6 % S.D.
Temperature: ±0.1 K.