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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,2-Dichlorobenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,2-Dichlorobenzene; C6H4Cl2; [95-50-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Wing, J.; Johnston, W.H., J. Am. Chem. Soc. 1957, 79(4), 864-5.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
1
* V
1
/V
2
[ml/dm**3]
10
2
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
3
* Mole Fraction x
1
x
1
Note
25
3.09 (a)
1.710
b
1.930
c
Method/Apparatus/Procedure:
Tritiated water was equilibrated with 20 ml 1,2-dichlorobenzene by stirring in a flask in a constant temperature water bath for two hours. The concentration of the tritiated water in the organic phase was determined by isotopic dilution. The tritium activities in the tritiated water samples were determined by the acetylene method (1,2). At least four independent experiments were done. The article was based upon work reported in a Ph.D. dissertation (2).
Source and Purity of Materials:
(1) Tracerlab Inc., tritiated water, used as received.
(2) Source not specified, chemical grade, redistilled before use.
Estimated Errors:
Solubility: ±1.5%.
Temperature: ±0.02 K.
References:
1
Wing, J.; Johnston, W. H. Science 1955, 121, 674-5.
2
Wing, J., Ph.D. Dissertation, Purdue University, Lafayette, 1956.