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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,2-Dichlorobenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,2-Dichlorobenzene; C6H4Cl2; [95-50-1]
NIST Chemistry WebBook
for detail
Original Measurements:
Kirchnerova, J.; Cave, G.C.B., Can. J. Chem. 1976, 54(24), 3909-16.
Variables:
Temperature = One temperature
Prepared By:
A. L. Horvath
Experimental Data:
(Notes on the Nomenclature)
t/°C
10
1
* g
1
/V
2
[g dm**-3]
10
2
* Concentration c
1
[mol dm**-3]
Concent. c
1
Note
10
3
* Mole Fraction x
1
x
1
Note
25
4.324
2.40
b
2.707
c
Notes:
a
Calculated by F. W. Getzen.
b
Reported.
c
Calculated by compiler.
Method/Apparatus/Procedure:
A mixture of 50 ml 1,2-dichlorobenzene and 6 ml water in a botte was submerged in a water thermostat bath for 2 days. The concentration of the water in the organic phase was determined by a conventional Karl Fischer dead stop back titration. Determinations were done in triplicate. A detailed description of the complete experimental procedure has been included in a Ph.D. dissertation (1).
Source and Purity of Materials:
(1) Distilled and deionized.
(2) Fisher - B255, washed with cc. H
2
SO
4
and K
2
SO
3
solution and distilled water. Dried over silica gel and fractionally distilled, purity 99.8%.
Estimated Errors:
Solubility: ±1%.
Temperature: ±0.1 K.
References:
1
Kirchnerova, J., Ph.D. Dissertation, McGill University, Montreal, Quebec, 1974.