IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1,3-Dichlorobenzene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,3-Dichlorobenzene; C6H4Cl2; [541-73-1]  NIST Chemistry WebBook for detail
Original Measurements:
   Banerjee, S.; Yalkowsky, S.H.; Valvani, S.C., Environ. Sci. Technol. 1980, 14, 1227-9.

 Variables:
   Temperature = One temperature

 Prepared By:
   A. L. Horvath

 Experimental Data:   (Notes on the Nomenclature)
  
t/°C101 * g1/V2 [g dm**-3]104 * Concentration c1 [mol dm**-3]Concent. c1 Note105 * Mole Fraction x1x1 Note
251.3359.08b1.641a
 Notes:
   a  Calculated by compiler.
   b  Reported.

 Method/Apparatus/Procedure:
   An excess of 1,3-dichlorobenzene was added to water in a stainless steel centrifuge tube which was then sealed. The equilibrium was established by allowing the sample to stand, with intermittent shaking, for a week at constant temperature. The mixture was then centrifuged and aliquots of the solution were removed either by a pipet or syringe for analysis. Liquid scintillation counting with 14C-labelled solute was employed in the solubility determinations. The entire procedure was carried out at least twice and each analysis was also conducted in duplicate.

 Source and Purity of Materials:
   (1) New England Nuclear, used as received.
   (2) Distilled.

 Estimated Errors:
   Solubility: ±1.1% S.D.
   Temperature: ±0.3 K.