IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 1,4-Dichlorobenzene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1,4-Dichlorobenzene; C6H4Cl2; [106-46-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Klemenc, A.; Low, M., Rec. Trav. Chim. Pays-Bas 1930, 49(4), 629-40.

Variables:
   Temperature = Temperature

Prepared By:
   A. L. Horvath

Experimental Data:   (Notes on the Nomenclature)
  
t/°C103 * Molality mol1/kgmol1/kg Note101 * g1/kgg1/kg Note105 * Mole Fraction x1x1 Note
551.061b1.56a1.912c
601.109b1.63a1.998c
Notes:
   a  Reported.
   b  Calculated by F. W. Getzen.
   c  Calculated by compiler.

Method/Apparatus/Procedure:
   The determination of the solubility was based upon volumetric principles applied to the measurement of excess solute in a calibrated apparatus as described by Rex (1).

Source and Purity of Materials:
   (1) Prepared by chlorination of benzene using iodine as catalyst. The preparate was recrystalized several times in ethanol before use, m.p. = 52.7°C.
   (2) Distilled.

Estimated Errors:
   Solubility: ±10% (compiler).
   Temperature: ± 1 K. (compiler).

References:
   1Rex, A. Z. Phys. Chem. 1906, 55(A), 355-70.