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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Benzene with Sodium Chloride and Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Benzene; C6H6; [71-43-2]
NIST Chemistry WebBook
for detail
(3) Sodium Chloride; NaCl; [7647-14-5]
NIST Chemistry WebBook
for detail
Original Measurements:
Price, L.C., Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.
Variables:
Temperature = One temperature: 25 °C
Concentration = Salinity: 1-360 g(2)/kg sln
Prepared By:
M. Kleinschmidt and D. Shiu
Experimental Data:
(Notes on the Nomenclature)
Solubility of Benzene in Aqueous NaCl
t/°C
g
2
/kg
g
1
/100 g solution
10
4
* Mole Fraction x
1
(compiler)
25
1.002
0.1718
3.96
25
10.000
0.1628
3.78
25
34.472 (a)
0.1391
3.28
25
50.030
0.1194
2.85
25
125.100
0.0593
1.48
25
199.900
0.0388
1.01
25
279.800
0.0214
0.581
25
358.700
0.0134
0.378
Notes:
Table 1
a
Artificial seawater, composition not specified but probably similar to ref 1.
Method/Apparatus/Procedure:
Details given in source. (1) was equilibrated with NaCl solution for one month. A aliquot was analyzed for one month. An aliquot was analysed directly by gas chromatography.
Source and Purity of Materials:
(1) commercial, 99+% pure
Estimated Errors:
Solubility: ± 10 relative %
Temperature: ± 1 K
References:
1
Lyman, J.; Fleming, R.H.; J. Mar. Res. 1940, 3, 135.