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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
2-Methyl-2-butene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 2-Methyl-2-butene; C5H10; [513-35-9]
NIST Chemistry WebBook
for detail
Original Measurements:
Pavlova, S.P.; Pavlov, S.Yu.; Serafimov, L.A.; Kofman, L.S., Promyshlennost. Sinteticheskogo Kauchuka 1966, 3, 18-20.
Variables:
Temperature = 20-60 °C
Prepared By:
A. Maczynski
Experimental Data:
(Notes on the Nomenclature)
Solubility of 2-methyl-2-butene in water
t/°C
g
1
/100 g solution (compiler)
10
5
* Mole Fraction x
1
20
0.0215
5.63
40
0.0236
6.06
50
0.0250
6.42
60
0.0267
6.87
Solubility of water in 2-methyl-2-butene
t/°C
g
2
/100 g solution (compiler)
10
3
* Mole Fraction x
2
20
0.0388
1.51
40
0.0589
2.29
60
0.0906
3.52
Method/Apparatus/Procedure:
The solubility of (1) in (2) was determined by glc. The solubility of (2) in (1) was determined by the Karl Fischer reagent method.
Source and Purity of Materials:
(1) source not specified; better than 99.7 wt%.
(2) doubly distilled.
Estimated Errors:
Temperature: ± 0.1 K