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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Toluene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Toluene; C7H8; [108-88-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Tarassenkow, D.N.; Poloshinzewa, E.N., Ber. Dtsch. Chem. Ges. 1932, 65B, 184-6.
Variables:
Temperature = (-9)-93 °C
Prepared By:
A. Maczynski and Z. Maczynska
Experimental Data:
(Notes on the Nomenclature)
Solubility of water in toluene
t/°C
g
2
/100 g solution
10
3
* Mole Fraction x
2
(compiler)
-9
0.002
0.1
-3.5
0.005
0.3
10.5
0.020
1.0
18
0.034
1.7
30
0.053
2.7
38.5
0.070
3.6
48
0.097
4.9
60.5
0.153
7.8
68
0.201
10.2
76
0.254
12.9
84
0.312
15.8
93
0.413
20.8
Method/Apparatus/Procedure:
Alexejew's method was used (ref 1). No additional details were reported in the paper.
Source and Purity of Materials:
(1) Kahlbaum, CP; dried ove calcium chloride and distilled from sodium; purity not specified.
(2) not specified.
Estimated Errors:
Solubility: ± 0.01% (not specified).
References:
1
Alexejew, W. Wied Ann. Physik 1886, 28, 35.