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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Toluene with Sodium Chloride and Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Sodium Chloride; NaCl; [7647-14-5]
NIST Chemistry WebBook
for detail
(3) Toluene; C7H8; [108-88-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Price, L.C., Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.
Variables:
Temperature = 25 °C
Concentration = Salinity: 1-360 g(2)/kg sln
Prepared By:
M. Kleinschmidt and D. Shaw
Experimental Data:
(Notes on the Nomenclature)
Solubility of Toluene in Aqueous NaCl
t/°C
g
2
/kg
g
1
/100 g solution
10
5
* Mole Fraction x
1
(compiler)
25
1.002
0.0526
10.3
25
10.000
0.0490
9.65
25
34.472
a
0.0402
8.04
25
50.030
0.0359
7.26
25
125.100
0.0182
3.85
25
199.900
0.0106
2.34
25
279.800
0.00538
1.24
25
358.700
0.00372
0.890
Notes:
Table 1
a
Artificial seawater, composition not specified but probably similar to ref 1.
Method/Apparatus/Procedure:
Details given in source. (1) was equilibrated with NaCl solution for one month. An aliquot was analyzed directly by gas chromatography.
Source and Purity of Materials:
(1) commercial, 99 + % pure
Estimated Errors:
Solubility: ± 10 relative %
Temperature: ± 1 K
References:
1
Lyman, J.; Fleming, R. H.;
J. Mar. Res.
1940
, 3, 135.