Home
Introduction
Search Menu
IUPAC Series (PDF)
Reference
Version History
About the Project
Disclaimer
Contact Us
Acknowledgements
IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
1,3,5-Cycloheptatriene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 1,3,5-Cycloheptatriene; C7H8; [544-25-2]
NIST Chemistry WebBook
for detail
Original Measurements:
Pierotti, R.A.; Liabastre, A.A., "Structure and properties of water solutions." U.S. Nat. Tech. Inform. Serv., PB Rep., 1972, No. 21163, 113 p.
Variables:
Temperature = 278.26-318.36 K
Prepared By:
M.C. Haulait-Pirson
Experimental Data:
(Notes on the Nomenclature)
Solubility of 1,3,5-cycloheptatriene in water
T/K
g
1
/100 g solution
10
3
* Mole Fraction x
1
278.26
0.05809 ± 0.0014
0.1136
288.36
0.06645 ± 0.0017
0.1299
298.26
0.06694 ± 0.0019
0.1309
308.36
0.07418 ± 0.0019
0.1450
318.36
0.07648 ± 0.0022
0.1495
Method/Apparatus/Procedure:
10 mL of (2) were placed along with 4-10 drops of (1) in 10 mL serum bottles, which were then tightly capped, and placed in the rotating basket and rotated for 24 hours. The bottled were then hand shaken to remove (1) droplets from the stoppers and then replaced in the bath with the tops down for an additional 24 hours. The solute concentrations were determined by use of a flame-ionization gas chromatograph. Many details about equipment, operating conditions and calculation are given in the paper.
Source and Purity of Materials:
(1) Columbia Organic Chemicals Co., Inc.; Tech 83%; used as received.
(2) laboratory distilled water.
Estimated Errors:
Solubility: standard deviation from at least 15 meausrements are given above.