IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: 2,4-Dimethylpentane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 2,4-Dimethylpentane; C7H16; [108-08-7]  NIST Chemistry WebBook for detail

Original Measurements:
   McAuliffe, C., Nature (London) 1963, 200, 1092-3.

Variables:
   Temperature = One temperature: 25 °C

Prepared By:
   M.C. Haulait-Pirson

Experimental Remarks:

   The solubility of 2,4-dimethylpentane in water at 25°C was reported to be 3.62 mg (1)/ kg sln (0.00362 g(1)/100 g sln).
The corresponding mole fraction, x1, calculated by the compiler, is 6.5 x 10-7.

Experimental Data:   (Notes on the Nomenclature)
   Method/Apparatus/Procedure:
   20-50 mL of 91) was added to 920 and vigorously shaken or stirred several days with a magnetic stirrer. A 0.05 mL or 0.10 mL water was directly injected into the gas chromatograph fitted with a suitable fractionator to absorb water. A hydrogen-flame ionization detector was used.

Source and Purity of Materials:
   (1) Phillips Petroleum Co.; 99+% purity; used as received.
   (2) distilled.

Estimated Errors:
   Solubility: 0.10 mg (10/kg sln (standard deviation from mean)
   Temperature: ± 1.5 K