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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
2,4-Dimethylpentane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 2,4-Dimethylpentane; C7H16; [108-08-7]
NIST Chemistry WebBook
for detail
Original Measurements:
McAuliffe, C., Nature (London) 1963, 200, 1092-3.
Variables:
Temperature = One temperature: 25 °C
Prepared By:
M.C. Haulait-Pirson
Experimental Remarks:
The solubility of 2,4-dimethylpentane in water at 25°C was reported to be 3.62 mg (1)/ kg sln (0.00362 g(1)/100 g sln).
The corresponding mole fraction,
x
1
, calculated by the compiler, is 6.5 x 10
-7
.
Experimental Data:
(Notes on the Nomenclature)
Method/Apparatus/Procedure:
20-50 mL of 91) was added to 920 and vigorously shaken or stirred several days with a magnetic stirrer. A 0.05 mL or 0.10 mL water was directly injected into the gas chromatograph fitted with a suitable fractionator to absorb water. A hydrogen-flame ionization detector was used.
Source and Purity of Materials:
(1) Phillips Petroleum Co.; 99+% purity; used as received.
(2) distilled.
Estimated Errors:
Solubility: 0.10 mg (10/kg sln (standard deviation from mean)
Temperature: ± 1.5 K