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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
2,4-Dimethylpentane with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) 2,4-Dimethylpentane; C7H16; [108-08-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Price, L.C., Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.
Variables:
Temperature = One temperature: 25 °C
Prepared By:
M.C. Haulait-Pirson
Experimental Remarks:
The solubility of 2,4-dimethylpentane in water at 25°C and at system pressure was reported to be 4.41 mg(1)/kg(2). The corresponding mass percent and mole fraction,
x
1
, calculated by the compiler are 4.41 x 10
-4
g(1)/100 g sln and 7.92 x 10
-7
.
Experimental Data:
(Notes on the Nomenclature)
Method/Apparatus/Procedure:
The solubility was determined at laboratory temperatures by use of screw-cap test tubes. The (1) phase floated on top of the water and insured saturation of the (2) phase in 2 to 4 days. Analyses were carried out by GLC using a Hewlett-Packard model 5751 gas chromatograph with dual-flame ionization detectors. Many details are givern in the paper.
Source and Purity of Materials:
(1) Phillips Petroleum Company; Chemical Samples Company or Aldrich Chemical Company; 99+%.
(2) distilled.
Estimated Errors:
Solubility: ± 0.05 mg(1)/kg(2)
Temperature: ± 1 K