IUPAC-NIST Solubilities Database

IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Solubility System: Nonane with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Nonane; C9H20; [111-84-2]  NIST Chemistry WebBook for detail

Evaluator:
   G.T. Hefter, School of Mathematical and Physical Sciences, Murdoch University, Perth, W.A., Australia. February 1986.

Critical Evaluation:

   Quantitative solubility data for the nonane (1) – water (2) system have been reported in the publications listed in Table 1.

The original data in all of these publications are compiled in the Data Sheets immediately following this Critical Evaluation. Roof (ref 4) has also reported a three phase critical point of unspecified composition at 555K and 8.5 MPa. For convenience further discussion of this system will be in two parts.

1. SOLUBILITY OF NONANE (1) IN WATER (2)

All the data available for the solubility of nonane in water are summarized in Table 2 with the exception of the datum of Krzyzanowska and Szeliga (ref 7) which does not appear to be independent of that of Price (ref 6) and has therefore been excluded from consideration

At 298K, the only temperature where comparison is possible, the agreement between the various studies is poor (Table 2) and the average must be regarded as Tentative only. Interestingly, the average value of 1.7 x 10^-5 g(1)/100g s1n is, however, quite close to the value of 2.0 x 10^-5 g(1)g s1n predicted by extrapolation of the lower n-alkane solubilities.

At other temperatures only the data of Jonsson et al. (ref 8) at 293K and Price (ref 6) at 303-410K are available and thus no Critical Evaluation is possible. There are also insufficient independent data to warrant plotting.

2. SOLUBILITY OF WATER (2) IN NONANE (1)

Only the single point data of Schatzberg (ref 1) at 298K and Benkovski et al. (ref 3) at 303K are available for the solubility of water in nonane and thus no Critical Evaluation is possible. The interested user is referred to the relevant Data Sheets for the experimental values; however, it may be noted that the data of Schatzberg (ref 1) are generally reliable.

Experimental Data:   (Notes on the Nomenclature)

Table 1. Quantitative Solubility Studies of the Nonane (1) - Water (2) System
Author	T/K	Reference	Solubility	Method
Schatzberg	298	1	(2) in (1)	Karl Fischer
McAuliffe	298	2	(1) in (2)	GLC
Benkovski et al.	303	3	(2) in (1)	Karl Fischer
Krasnoshchekova and Gubergrits	298	5	(1) in (2)	GLC
Price	298-410	6	(1) in (2)	GLC
Krzyzanowska and Szeliga	298	7	(1) in (2)	GLC
Jonsson et al.	288, 293	8	(1) in (2)	partition coefficient

Table 2. Tentative Solubility Values for Nonane (1) in Water (2)
T/K	Reference	Sol. Power	Solubility	Sol. Note	Best Sol. Power	Best Solubility	Best Sol. Note	x₁ Power	x₁	x₁ Note
293	8	5	2.89 g(1)/100g sln	a	5	2.9 g(1)/100g sln	b	8	4.1	b
298	2, 5, 6, 8	5	2.2, 0.71, 1.22, 2.72 g(1)/100g sln	a	5	1.7 ± 0.8 g(1)/100g sln	b	8	2.4	b
303	6	5	1.4* g(1)/100g sln	a	5	1.4 g(1)/100g sln	b	8	2.0	b
313	6	5	1.7* g(1)/100g sln	a	5	1.7 g(1)/100g sln	b	8	2.4	b
323	6	5	2.2* g(1)/100g sln	a	5	2.2 g(1)/100g sln	b	8	3.1	b
333	6	5	2.6* g(1)/100g sln	a	5	2.6 g(1)/100g sln	b	8	3.7	b
343	6	5	3.1* g(1)/100g sln	a	5	3.1 g(1)/100g sln	b	8	4.4	b
353	6	5	3.4* g(1)/100g sln	a	5	3.4 g(1)/100g sln	b	8	4.8	b
363	6	5	3.7* g(1)/100g sln	a	5	3.7 g(1)/100g sln	b	8	5.2	b
373	6	5	4.2* g(1)/100g sln	a	5	4.2 g(1)/100g sln	b	8	5.9	b
383	6	5	8.0* g(1)/100g sln	a	5	8.0 g(1)/100g sln	b	8	11	b
393	6	5	16* g(1)/100g sln	a	5	16 g(1)/100g sln	b	8	22	b
403	6	5	32* g(1)/100g sln	a	5	32 g(1)/100g sln	b	8	45	b

Notes:
Table 2^a  Values marked with an asterisk (*) have been obtained by the Evaluator by graphical interpolation of the author's original data.
Table 2^b  Obtained by averaging where appropriate; σ_n has no statistical significance.

References: (Click a link to see its experimental data associated with the reference)

   1  Schatzberg, P., J. Phys. Chem. 1963, 67, 776-9.
   2  McAuliffe, C., Science 1969, 163, 478-9.
   3  Benkovski, V.G.; Nauruzov, M.H.; Bogoslovaskaya, T.M., Tr. Inst. Khim. Nefti Prir. Solei Akad. Nauk Kaz. SSR 1970, 2, 25-32.
   4  Roof, J.G., J. Chem. Eng. Data 1970, 15, 301-3.
   5  Krasnoschchekova, R.Ya.; Gubergrits, M.Ya., Neftekhimiya 1973, 13, 885-8.
   6  Price, L.C., Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.
   7  Krzyzanowska, T.; Szeliga, J., Nafta (Katowice) 1978, 12, 413-7.
   8  Jonsson, J.A.; Vejrosta, J.; Novak, J., Fluid Phase Equil. 1982, 9, 279-86.