IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Naphthalene with Sodium chloride and Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Naphthalene; C10H8; [91-20-3]  NIST Chemistry WebBook for detail
   (3) Sodium chloride; NaCl; [7647-14-5]  NIST Chemistry WebBook for detail

Original Measurements:
   Gordon, J.E.; Thorne, R.L., J. Phys. Chem. 1967, 71, 4390-9.

Variables:
   Temperature = 24.91 °C   
pH = Salinity: 0-108 g (2)/kg sln
   Concentration = Salinity: 0-108 g (2)/kg sln

Prepared By:
   M. Kleinschmidt and D. Shaw

Experimental Remarks:

   The solubility of naphthalene in aqueous sodium chloride is reported in terms of the Setschenow equation:

log(So/S) = KsCs

where, So is the solubility of naphthalene in water (mol/L); S is the solubility of naphthalene in solution (mol/L); Ks is the Setschenow constant (L/mol); Cs is the concentration of sodium chloride (mol/L)

evaluating the equation for S over the range of Cs 0-2 mol/L, log So = –3.590 ± 0.004 (95% confidence limit) and Ks = 0.220 ± 0.0041 (95% confidence limit).

The corresponding mass percent and mole fraction, x1 at salinity = 35 g(2)/kg sln calculated by the compilers are 2.36 × 10–3 g(1)/100 g sln and 3.48 × 10–6 assuming a solution density of 1.025 kg/L.

Experimental Data:   (Notes on the Nomenclature)
   Method/Apparatus/Procedure:
   Saturated solutions were prepared by equilibrating excess (1) in salt water in sealed ampols for 24 hrs. After filtration the absorbance was measured with a UV spectrophotometer at three wavelengths.

Source and Purity of Materials:
   (1) recrystallized four times and sublimed or zone refined, 99.99+% pure,
   (2) analytical reagent grade,
   (3) distilled from potassium permanganate and redistilled from all glass still.

Estimated Errors:
   Solubility: see above.
   Temperature: ± 0.03°C