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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
sec-Butylbenzene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) sec-Butylbenzene; C10H14; [135-98-8]
NIST Chemistry WebBook
for detail
Evaluator:
A. Maczynski, Institute of Physical Chemistry of the Polish Academy of Sciences, Warszawa, Poland. November 1981.
Critical Evaluation:
The solubility of sec-butylbenzene (1) water (2) has been reported in three works listed below.
The data of Andrews and Keefer seem to be high. The mean value of the remaining data is tentative.
The solubility of water (2) in sec-butylbenzene (1) has been reported in one work listed below:
Since these data are from one source only, they are regarded as tentative.
Experimental Data:
(Notes on the Nomenclature)
Table 1. Solubility of sec-Butylbenzene 1) in Water (2)
Author
T/K
Reference
Solubility
Method
Andrews and Keefer
298.15
1
0.0309 g(1)/100 kg sln
spectrophotometric
Sutton and Calder
298.15
3
0.00176 g(1)/100 kg sln
GLC
Krzyzanowska and Szeliga
298.15
4
0.00101 g(1)/100 kg sln
GLC
Table 2. Solubility of Water (2) in sec-Butylbenzene (2) Tentative Value
Author
T/K
Reference
Method
Englin
et al.
273.15-323.15
2
gasometric
Table 3. Solubility of sec-Butylbenzene (1) in Water (2) Tentative Value
T/K
Solubility
x
1
x
1
x10(**)
298
0.0014 g(1)/100 g sln
1.9 × 10
-6
Table 4. Solubility of Water (2) in Sec-Butylbenzene (1) Tentative Values
T/K
Solubility
x
2
283
0.020 g(2)/100 g sln
0.0020
293
0.029 g(2)/100 g sln
0.0029
303
0.039 g(2)/100 g sln
0.0038
References: (Click a link to see its experimental data associated with the reference)
1
Andrews, L.J.; Keefer, R.M., J. Am. Chem. Soc. 1950, 72, 5034-7.
2
Englin, B.A.; Plate, A.F.; Tugolukov, V.M. Pryanishnikova, M.A., Khim. Tekhnol. Topl. Masel 1965, 10, 42-6.
3
Sutton, C.; Calder, J.A., J. Chem. Eng. Data 1975, 20, 320-2.
4
Krzyzanowska, T.; Szeliga, J., Nafta (Katowice) 1978, 12, 413-7.