IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: sec-Butylbenzene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) sec-Butylbenzene; C10H14; [135-98-8]  NIST Chemistry WebBook for detail

Evaluator:
   A. Maczynski, Institute of Physical Chemistry of the Polish Academy of Sciences, Warszawa, Poland. November 1981.

Critical Evaluation:

   The solubility of sec-butylbenzene (1) water (2) has been reported in three works listed below.

The data of Andrews and Keefer seem to be high. The mean value of the remaining data is tentative.

The solubility of water (2) in sec-butylbenzene (1) has been reported in one work listed below:

Since these data are from one source only, they are regarded as tentative.



Experimental Data:   (Notes on the Nomenclature)

Table 1. Solubility of sec-Butylbenzene 1) in Water (2)
AuthorT/KReferenceSolubilityMethod
Andrews and Keefer298.1510.0309 g(1)/100 kg slnspectrophotometric
Sutton and Calder298.1530.00176 g(1)/100 kg slnGLC
Krzyzanowska and Szeliga298.1540.00101 g(1)/100 kg slnGLC
Table 2. Solubility of Water (2) in sec-Butylbenzene (2) Tentative Value
AuthorT/KReferenceMethod
Englin et al.273.15-323.152gasometric
Table 3. Solubility of sec-Butylbenzene (1) in Water (2) Tentative Value
T/KSolubilityx1x1x10(**)
2980.0014 g(1)/100 g sln1.9 × 10-6
Table 4. Solubility of Water (2) in Sec-Butylbenzene (1) Tentative Values
T/KSolubilityx2
2830.020 g(2)/100 g sln0.0020
2930.029 g(2)/100 g sln0.0029
3030.039 g(2)/100 g sln0.0038
References: (Click a link to see its experimental data associated with the reference)

   1  Andrews, L.J.; Keefer, R.M., J. Am. Chem. Soc. 1950, 72, 5034-7.
   2  Englin, B.A.; Plate, A.F.; Tugolukov, V.M. Pryanishnikova, M.A., Khim. Tekhnol. Topl. Masel 1965, 10, 42-6.
   3  Sutton, C.; Calder, J.A., J. Chem. Eng. Data 1975, 20, 320-2.
   4  Krzyzanowska, T.; Szeliga, J., Nafta (Katowice) 1978, 12, 413-7.