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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Biphenyl with Seawater
Components:
(1) Biphenyl; C12H10; [92-52-4]
NIST Chemistry WebBook
for detail
(2) Seawater; ; []
NIST Chemistry WebBook
for detail
Evaluator:
D.G. Shaw, Institute of Marine Science, University of Alaska, Fairbanks, Alaska USA. December 1982.
Critical Evaluation:
The solubility of biphenyl (1) in seawater (2) at 298 K has been reported in two works.
The reported data are all from different salinities, which precludes direct comparison. Since the data appear consistent with each other and with the recommended value for the solubility of biphenyl in pure water, the data of Paul and of Eganhouse and Calder are adopted as tentative.
Experimental Data:
(Notes on the Nomenclature)
Table 1. Solubilty of Biphenyl (1) in Seawater (2) at 298 K
Author
Reference
Sol. Power
Solubility
Salinity
Method
Paul
1
4
6.08 - 3.45 10
4
g(1)/100 g sln
13-64 g salts/kg sln
uv spectral
Eganhouse and Calder
2
4
4.76 10
4
g(1)/100 g sln
35 g salts/kg sln
GLC
Table 2. Solubility of Biphenyl (1) in Seawater (2) Tentative Value
T/K
Sol. Power
Solubility
Salinity
298
4
4.76 10
4
g(1)/100 g sln
35 g salts/ kg sln
References: (Click a link to see its experimental data associated with the reference)
1
Paul, M.A., J. Am. Chem. Soc. 1952, 74, 5274-7.
2
Eganhouse, R.P.; Calder, J.A., Geochim. Cosmochim. Acta 1976, 40, 555-61.