IUPAC-NIST Solubility Database
NIST Standard Reference Database 106

Glass Ball as Bullet Solubility System: 1-Methylphenanthrene with Water
Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) 1-Methylphenanthrene; C15H12; [832-69-6]  NIST Chemistry WebBook for detail
Original Measurements:
   

 Variables:


Prepared By:
   

 Experimental Data:   (Notes on the Nomenclature)
  
Solubility of 1-methylphenanthrene in water
t/°Cg1/100 g solution (compiler)g1/100 g soln. Note (compiler)108 * Mole Fraction x1 (compiler)
6.60.95250.892
8.91.1451.07
14.01.4751.38
19.21.9351.81
24.12.5552.39
25.02.6952.69
26.93.0452.85
29.93.5553.32
 Method/Apparatus/Procedure:
   The dynamic coupled column liquid chromatography (DCCLC) method was based on generating saturated solutions by pumping water through a column packed with glass beads that have been coated with the component (1) (generator column). The concentration of (1) in the effluent of the generator column was measured by a modification of the coupled column liquid chromatographic process that has been described in ref 1.

 Source and Purity of Materials:
   (1) Commercial product; less than 3% impurities.
   (2) Distilled over KMnO4 and NaOH and passed through a column packed with XAD-2 (Rohm and Hass, Philadelphia, Pa).

 Estimated Errors:
   Solubility: stand. dev. See above.
   Temperature: ± 0.05 °C

 References:
   1May, W.; Chesler, S.; Cram, S.; Gump, B.; Hertz, H.; Enagonio, D.; Dyszel, S., J. Chromatogr. Sci. 1975, 13, 535.