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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Dibenz[a,h]anthracene with Water
Components:
(1) Water; H2O; [7732-18-5]
NIST Chemistry WebBook
for detail
(2) Dibenz[a,h]anthracene; C22H14; [58-70-3]
NIST Chemistry WebBook
for detail
Evaluator:
G.T. Hefter, School of Mathematical and Physical Sciences, Murdoch University, Perth, W.A., Australia. June 1986.
Critical Evaluation:
Quantitative solubility data for dibenz[a,h]anthracene (1) in water (2) have been reported in the publications listed in Table 1. No data are available for the solubility of water in dibenz[a,h]anthracene.
The original data and related information in both of these publications are compiled in the Data Sheets immediately following this Critical Evaluation. The data are also summarized in Table 2 below. The two reported values, although obtained at slightly different temperatures, are in excellent agreement. Nevertheless there are insufficient data and the system is insufficiently well-characterized to justify a higher than Tentative classification.
Experimental Data:
(Notes on the Nomenclature)
Table 1. Quantitative Solubility Studies of Dibenz[a, h]anthracene (1) in Water (2)
Author
T/K
Reference
Method
Davis
et al.
300
1
nephelometric
Klevens
298
2
spectrophotometric
Table 2. Tentative Solubility Values of Dibenz[a, h]anthracene (1) in Water (2)
T/K
Reference
Sol. Power
Solubility
Best Sol. Power
Best Solubility
x
1
Power
x
1
298
2
8
5.84 g(1)/100g sln
8
6 g(1)/100g sln
11
4
300
1
8
5 g(1)/100g sln
8
5 g(1)/100g sln
11
3
References: (Click a link to see its experimental data associated with the reference)
1
Davis, W.W.; Krahl, M.E.; Cloves, G.H.A., J. Am. Chem. Soc. 1942, 64, 108-10.
2
Klevens, H.B., J. Phys. Chem. 1950, 54, 283-98.