IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Dibenz[a,h]anthracene with Water

Components:
   (1) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (2) Dibenz[a,h]anthracene; C22H14; [58-70-3]  NIST Chemistry WebBook for detail

Evaluator:
   G.T. Hefter, School of Mathematical and Physical Sciences, Murdoch University, Perth, W.A., Australia. June 1986.

Critical Evaluation:

   Quantitative solubility data for dibenz[a,h]anthracene (1) in water (2) have been reported in the publications listed in Table 1. No data are available for the solubility of water in dibenz[a,h]anthracene.

The original data and related information in both of these publications are compiled in the Data Sheets immediately following this Critical Evaluation. The data are also summarized in Table 2 below. The two reported values, although obtained at slightly different temperatures, are in excellent agreement. Nevertheless there are insufficient data and the system is insufficiently well-characterized to justify a higher than Tentative classification.



Experimental Data:   (Notes on the Nomenclature)

Table 1. Quantitative Solubility Studies of Dibenz[a, h]anthracene (1) in Water (2)
AuthorT/KReferenceMethod
Davis et al.3001nephelometric
Klevens2982spectrophotometric
Table 2. Tentative Solubility Values of Dibenz[a, h]anthracene (1) in Water (2)
T/KReferenceSol. PowerSolubilityBest Sol. PowerBest Solubilityx1 Powerx1
298285.84 g(1)/100g sln86 g(1)/100g sln114
300185 g(1)/100g sln85 g(1)/100g sln113
References: (Click a link to see its experimental data associated with the reference)

   1  Davis, W.W.; Krahl, M.E.; Cloves, G.H.A., J. Am. Chem. Soc. 1942, 64, 108-10.
   2  Klevens, H.B., J. Phys. Chem. 1950, 54, 283-98.