IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ethene with Ethane and Water

Components:
   (1) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail
   (2) Water; H2O; [7732-18-5]  NIST Chemistry WebBook for detail
   (3) Ethane; C2H6; [74-84-0]  NIST Chemistry WebBook for detail

Original Measurements:
   Anthony, R.G.; McKetta, J.J., J. Chem. Eng. Data 1967, 12, 21-28.

Variables:
   Temperature = 310.9 K to 410.9 K
   Pressure = 3.47 to 34.60 MPa
   Concentration = 0 - 1 (y1/mole fraction)

Prepared By:
   W. Hayduk

Experimental Remarks:

   It was shown that Henry's law was obeyed for both gas components for the complete pressure range to 4000 psia.

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
  
T/KPressure [psia]Pressure [MPa]Pressure Note103 * Mole Fraction (x1)x1 Note103 * Mole Fraction (x2)x2 NoteMole Fraction of Gas (y1)y1 NoteMole Fraction of Gas (y2)y2 Note
310.93 ± 0.06503.23.46911.2756Liquid Phase, Ethene0.1993Liquid Phase, Ethane0.72511 Gas Phase Mole Fraction, Ethene0.2741 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.06503.23.46911.0820Liquid Phase, Ethene0.2520Liquid Phase, Ethane0.59671 Gas Phase Mole Fraction, Ethene0.4033 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.06504.23.47610.9493Liquid Phase, Ethene0.2905Liquid Phase, Ethane0.54831 Gas Phase Mole Fraction, Ethene0.4517 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.06503.73.42910.3692Liquid Phase, Ethene0.5616Liquid Phase, Ethane0.18451 Gas Phase Mole Fraction, Ethene0.8154 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.06995.76.86510.8030Liquid Phase, Ethene0.589Liquid Phase, Ethane0.26921 Gas Phase Mole Fraction, Ethene0.7308 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061000.76.90010.2007Liquid Phase, Ethene0.761Liquid Phase, Ethane0.07921 Gas Phase Mole Fraction, Ethene0.9205 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061000.76.90012.162Liquid Phase, Ethene0.238Liquid Phase, Ethane0.76131 Gas Phase Mole Fraction, Ethene0.2387 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.17503.93.47410.9790Liquid Phase, Ethene0.0980Liquid Phase, Ethane0.77991 Gas Phase Mole Fraction, Ethene0.2201 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.17503.23.46910.9090Liquid Phase, Ethene0.0920Liquid Phase, Ethane0.78851 Gas Phase Mole Fraction, Ethene0.2115 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.17500.73.45210.7982Liquid Phase, Ethene0.1289Liquid Phase, Ethane0.67161 Gas Phase Mole Fraction, Ethene0.3284 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.17501.73.45910.5666Liquid Phase, Ethene0.2194Liquid Phase, Ethane0.48781 Gas Phase Mole Fraction, Ethene0.5122 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.17504.73.48010.1269Liquid Phase, Ethene0.3723Liquid Phase, Ethane0.10791 Gas Phase Mole Fraction, Ethene0.8921 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171002.26.91010.9597Liquid Phase, Ethene0.425Liquid Phase, Ethane0.39341 Gas Phase Mole Fraction, Ethene0.6066 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171005.26.93110.3698Liquid Phase, Ethene0.5783Liquid Phase, Ethane0.16431 Gas Phase Mole Fraction, Ethene0.8357 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171499.210.33711.4684Liquid Phase, Ethene0.4396Liquid Phase, Ethane0.50751 Gas Phase Mole Fraction, Ethene0.4925 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171004.26.92410.9107Liquid Phase, Ethene0.3593Liquid Phase, Ethane0.39321 Gas Phase Mole Fraction, Ethene0.6068 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171491.210.28110.9977Liquid Phase, Ethene0.5653Liquid Phase, Ethane0.34751 Gas Phase Mole Fraction, Ethene0.6525 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171008.76.99511.852Liquid Phase, Ethene0.1122Liquid Phase, Ethane0.85191 Gas Phase Mole Fraction, Ethene0.1481 x 1001 Gas Phase Mole Fraction, Ethane
377.59 ± 0.171499.210.33712.3379Liquid Phase, Ethene0.1901Liquid Phase, Ethane0.80571 Gas Phase Mole Fraction, Ethene0.1943 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061080.27.44810.0030Liquid Phase, Ethene0.8810Liquid Phase, Ethane0.00941 Gas Phase Mole Fraction, Ethene0.9906 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061503.210.36410.2452Liquid Phase, Ethene0.7531Liquid Phase, Ethane0.05401 Gas Phase Mole Fraction, Ethene0.9460 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061486.210.24710.4087Liquid Phase, Ethene0.7663Liquid Phase, Ethane0.23241 Gas Phase Mole Fraction, Ethene0.8676 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061521.210.48811.1368Liquid Phase, Ethene0.5472Liquid Phase, Ethane0.34401 Gas Phase Mole Fraction, Ethene0.6560 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061505.210.37812.417Liquid Phase, Ethene0.2517Liquid Phase, Ethane0.75771 Gas Phase Mole Fraction, Ethene0.2423 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061994.213.74912.4870Liquid Phase, Ethene0.2550Liquid Phase, Ethane0.74301 Gas Phase Mole Fraction, Ethene0.2570 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061513.210.43312.417Liquid Phase, Ethene0.2463Liquid Phase, Ethane0.72991 Gas Phase Mole Fraction, Ethene0.2701 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061992.213.73612.5018Liquid Phase, Ethene0.2932Liquid Phase, Ethane0.73611 Gas Phase Mole Fraction, Ethene0.2639 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061992.213.78411.9589Liquid Phase, Ethene0.4275Liquid Phase, Ethane0.57731 Gas Phase Mole Fraction, Ethene0.4227 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.061975.213.61810.5006Liquid Phase, Ethene0.7694Liquid Phase, Ethane0.15091 Gas Phase Mole Fraction, Ethene0.8491 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063001.720.69610.6561Liquid Phase, Ethene1.099Liquid Phase, Ethane0.16761 Gas Phase Mole Fraction, Ethene0.8324 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.112010.213.86010.6556Liquid Phase, Ethene0.676Liquid Phase, Ethane0.20421 Gas Phase Mole Fraction, Ethene0.7958 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111519.210.47410.6098Liquid Phase, Ethene0.651Liquid Phase, Ethane0.21401 Gas Phase Mole Fraction, Ethene0.7860 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.112010.213.86010.4624Liquid Phase, Ethene0.5644Liquid Phase, Ethane0.21701 Gas Phase Mole Fraction, Ethene0.7830 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11502.23.46310.2671Liquid Phase, Ethene0.3508Liquid Phase, Ethane0.22601 Gas Phase Mole Fraction, Ethene0.7740 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.112015.213.89411.4237Liquid Phase, Ethene0.468Liquid Phase, Ethane0.45281 Gas Phase Mole Fraction, Ethene0.5472 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111504.210.37111.2906Liquid Phase, Ethene0.437Liquid Phase, Ethane0.47321 Gas Phase Mole Fraction, Ethene0.5268 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11997.76.87911.105Liquid Phase, Ethene0.3645Liquid Phase, Ethane0.46501 Gas Phase Mole Fraction, Ethene0.5350 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11502.23.46310.6212Liquid Phase, Ethene0.2386Liquid Phase, Ethane0.47191 Gas Phase Mole Fraction, Ethene0.5281 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111999.213.78412.1715Liquid Phase, Ethene0.271Liquid Phase, Ethane0.70251 Gas Phase Mole Fraction, Ethene0.2975 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111514.210.44012.3429Liquid Phase, Ethene0.474Liquid Phase, Ethane0.68971 Gas Phase Mole Fraction, Ethene0.3103 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11995.76.86511.5887Liquid Phase, Ethene0.2353Liquid Phase, Ethane0.69891 Gas Phase Mole Fraction, Ethene0.3011 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11504.83.48010.9686Liquid Phase, Ethene0.1494Liquid Phase, Ethane0.30831 Gas Phase Mole Fraction, Ethene0.6917 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111494.210.30210.8966Liquid Phase, Ethene0.547Liquid Phase, Ethane0.32191 Gas Phase Mole Fraction, Ethene0.6781 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111990.213.72210.2930Liquid Phase, Ethene0.788Liquid Phase, Ethane0.10501 Gas Phase Mole Fraction, Ethene0.8950 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.111514.210.44010.2809Liquid Phase, Ethene0.710Liquid Phase, Ethane0.10041 Gas Phase Mole Fraction, Ethene0.8996 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11995.76.86510.2252Liquid Phase, Ethene0.698Liquid Phase, Ethane0.10671 Gas Phase Mole Fraction, Ethene0.8933 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.11298.22.05610.1144Liquid Phase, Ethene0.331Liquid Phase, Ethane0.11491 Gas Phase Mole Fraction, Ethene0.8851 x 1001 Gas Phase Mole Fraction, Ethane
410.65504.73.48010.9286Liquid Phase, Ethene0.1274Liquid Phase, Ethane0.71701 Gas Phase Mole Fraction, Ethene0.2830 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061009.26.95810.6304Liquid Phase, Ethene0.6166Liquid Phase, Ethane0.24401 Gas Phase Mole Fraction, Ethene0.7560 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.06503.73.47310.3275Liquid Phase, Ethene0.3485Liquid Phase, Ethane0.26301 Gas Phase Mole Fraction, Ethene0.7370 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061500.210.34311.4217Liquid Phase, Ethene0.6923Liquid Phase, Ethane0.45531 Gas Phase Mole Fraction, Ethene0.5447 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061002.26.91011.0230Liquid Phase, Ethene0.4530Liquid Phase, Ethane0.43831 Gas Phase Mole Fraction, Ethene0.5617 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.06512.23.53110.5422Liquid Phase, Ethene0.2718Liquid Phase, Ethane0.45101 Gas Phase Mole Fraction, Ethene0.5490 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061496.210.31612.3140Liquid Phase, Ethene0.2889Liquid Phase, Ethane0.72681 Gas Phase Mole Fraction, Ethene0.2732 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061009.26.95811.7225Liquid Phase, Ethene0.2405Liquid Phase, Ethane0.73491 Gas Phase Mole Fraction, Ethene0.2651 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061494.210.30210.8261Liquid Phase, Ethene0.8060Liquid Phase, Ethane0.24601 Gas Phase Mole Fraction, Ethene0.7540 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061996.213.76310.9168Liquid Phase, Ethene0.8862Liquid Phase, Ethane0.25041 Gas Phase Mole Fraction, Ethene0.7496 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.065019.734.60911.9548Liquid Phase, Ethene0.6492Liquid Phase, Ethane0.45121 Gas Phase Mole Fraction, Ethene0.5488 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.064004.727.61111.7366Liquid Phase, Ethene0.5823Liquid Phase, Ethane0.44121 Gas Phase Mole Fraction, Ethene0.5588 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063007.720.73711.5942Liquid Phase, Ethene0.5748Liquid Phase, Ethane0.43451 Gas Phase Mole Fraction, Ethene0.5655 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.065004.734.50611.0773Liquid Phase, Ethene0.8257Liquid Phase, Ethane0.25861 Gas Phase Mole Fraction, Ethene0.7414 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.064004.727.61111.0084Liquid Phase, Ethene0.7635Liquid Phase, Ethane0.25151 Gas Phase Mole Fraction, Ethene0.7485 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063001.520.69410.9739Liquid Phase, Ethene0.7061Liquid Phase, Ethane0.25591 Gas Phase Mole Fraction, Ethene0.7441 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.065022.734.63012.6492Liquid Phase, Ethene0.4198Liquid Phase, Ethane0.62691 Gas Phase Mole Fraction, Ethene0.3731 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.064002.227.59412.4916Liquid Phase, Ethene0.4133Liquid Phase, Ethane0.63471 Gas Phase Mole Fraction, Ethene0.3653 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063014.720.78612.3585Liquid Phase, Ethene0.3804Liquid Phase, Ethane0.63641 Gas Phase Mole Fraction, Ethene0.3636 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.065004.734.50613.0824Liquid Phase, Ethene0.3236Liquid Phase, Ethane0.73041 Gas Phase Mole Fraction, Ethene0.2696 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063999.727.57713.0453Liquid Phase, Ethene0.2927Liquid Phase, Ethane0.73131 Gas Phase Mole Fraction, Ethene0.2687 x 1001 Gas Phase Mole Fraction, Ethane
310.93 ± 0.063007.220.73412.7411Liquid Phase, Ethene0.2588Liquid Phase, Ethane0.72611 Gas Phase Mole Fraction, Ethene0.2729 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.115008.734.53412.981Liquid Phase, Ethene0.3126Liquid Phase, Ethane0.72891 Gas Phase Mole Fraction, Ethene0.2711 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.114010.727.65312.7889Liquid Phase, Ethene0.2900Liquid Phase, Ethane0.73421 Gas Phase Mole Fraction, Ethene0.2658 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.113014.720.78612.5599Liquid Phase, Ethene0.2781Liquid Phase, Ethane0.73031 Gas Phase Mole Fraction, Ethene0.2697 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.115000.734.47911.155Liquid Phase, Ethene0.7477Liquid Phase, Ethane0.32211 Gas Phase Mole Fraction, Ethene0.6779 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.114004.734.50611.1637Liquid Phase, Ethene0.7003Liquid Phase, Ethane0.30781 Gas Phase Mole Fraction, Ethene0.6922 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.113008.720.74411.0637Liquid Phase, Ethene0.6413Liquid Phase, Ethane0.29891 Gas Phase Mole Fraction, Ethene0.7011 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.114998.734.46510.6710Liquid Phase, Ethene0.8778Liquid Phase, Ethane0.18381 Gas Phase Mole Fraction, Ethene0.8162 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.114002.727.59810.6822Liquid Phase, Ethene0.8188Liquid Phase, Ethane0.18561 Gas Phase Mole Fraction, Ethene0.8144 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.113007.720.73710.6163Liquid Phase, Ethene0.7336Liquid Phase, Ethane0.18151 Gas Phase Mole Fraction, Ethene0.8185 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.115000.034.47410.2627Liquid Phase, Ethene0.9484Liquid Phase, Ethane0.08311 Gas Phase Mole Fraction, Ethene0.9169 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.114009.727.64610.3120Liquid Phase, Ethene0.9120Liquid Phase, Ethane0.08141 Gas Phase Mole Fraction, Ethene0.9186 x 1001 Gas Phase Mole Fraction, Ethane
344.26 ± 0.113004.720.71710.2771Liquid Phase, Ethene0.8529Liquid Phase, Ethane0.07751 Gas Phase Mole Fraction, Ethene0.9225 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.064015.727.68711.2314Liquid Phase, Ethene0.9076Liquid Phase, Ethane0.27301 Gas Phase Mole Fraction, Ethene0.7270 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.063004.720.71711.0655Liquid Phase, Ethene0.8025Liquid Phase, Ethane0.27531 Gas Phase Mole Fraction, Ethene0.7247 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.062012.213.87410.8968Liquid Phase, Ethene0.7052Liquid Phase, Ethane0.27551 Gas Phase Mole Fraction, Ethene0.7245 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.064009.727.64612.4124Liquid Phase, Ethene0.5428Liquid Phase, Ethane0.55991 Gas Phase Mole Fraction, Ethene0.4401 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.063012.720.77212.1783Liquid Phase, Ethene0.5067Liquid Phase, Ethane0.56081 Gas Phase Mole Fraction, Ethene0.4392 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.062010.213.86011.856Liquid Phase, Ethene0.4499Liquid Phase, Ethane0.56261 Gas Phase Mole Fraction, Ethene0.4374 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.063997.727.56313.1954Liquid Phase, Ethene0.3586Liquid Phase, Ethane0.73921 Gas Phase Mole Fraction, Ethene0.2637 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.063008.720.74412.9466Liquid Phase, Ethene0.3384Liquid Phase, Ethane0.74921 Gas Phase Mole Fraction, Ethene0.2608 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.062012.213.87412.4448Liquid Phase, Ethene0.2545Liquid Phase, Ethane0.74131 Gas Phase Mole Fraction, Ethene0.2587 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.064014.727.68010.3900Liquid Phase, Ethene1.093Liquid Phase, Ethane0.09471 Gas Phase Mole Fraction, Ethene0.9053 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.063010.720.75810.3680Liquid Phase, Ethene1.012Liquid Phase, Ethane0.08881 Gas Phase Mole Fraction, Ethene0.9112 x 1001 Gas Phase Mole Fraction, Ethane
377.54 ± 0.062011.213.86710.2998Liquid Phase, Ethene0.9072Liquid Phase, Ethane0.09601 Gas Phase Mole Fraction, Ethene0.9040 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.063009.720.75110.7372Liquid Phase, Ethene1.237Liquid Phase, Ethane0.16751 Gas Phase Mole Fraction, Ethene0.8325 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.062009.213.85310.5967Liquid Phase, Ethene1.0313Liquid Phase, Ethane0.15231 Gas Phase Mole Fraction, Ethene0.8477 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061503.210.36410.4923Liquid Phase, Ethene0.8897Liquid Phase, Ethane0.16641 Gas Phase Mole Fraction, Ethene0.8336 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.062993.720.64112.0783Liquid Phase, Ethene0.8337Liquid Phase, Ethane0.42381 Gas Phase Mole Fraction, Ethene0.5762 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.062000.213.79111.6548Liquid Phase, Ethene0.7022Liquid Phase, Ethane0.43721 Gas Phase Mole Fraction, Ethene0.5628 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061506.710.38811.3830Liquid Phase, Ethene1.5970Liquid Phase, Ethane0.43921 Gas Phase Mole Fraction, Ethene0.5608 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.063002.220.69912.9936Liquid Phase, Ethene0.5504Liquid Phase, Ethane0.62471 Gas Phase Mole Fraction, Ethene0.3753 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061999.213.78412.3747Liquid Phase, Ethene0.4523Liquid Phase, Ethane0.63381 Gas Phase Mole Fraction, Ethene0.3662 x 1001 Gas Phase Mole Fraction, Ethane
410.93 ± 0.061504.710.37511.9190Liquid Phase, Ethene0.3820Liquid Phase, Ethane0.63931 Gas Phase Mole Fraction, Ethene0.3606 x 1001 Gas Phase Mole Fraction, Ethane
Notes:
   1  Calculated by compiler.

Method/Apparatus/Procedure:
   The apparatus consisted of a high pressure cell mounted in a thermostat and equipped for mixing and pressure measurement. A water analyzer was used for the water vapor content of the vapor phase. The water phase was sampled and analyzed by means of an absolute manometer and an Orsat gas burette. To maintain equilibrium in the cell during sampling, a volume of mercury was injected into the cell equal to that of the saturated solution withdrawn. The hydrocarbon was desorbed at low pressure in the gas burette at constant temperature, and then the gas volume and pressure was determined. The gas was also analyzed.

Details are given in Ref. 1 and 2.

Source and Purity of Materials:
   1. Ethene minimum purity 99.3%.
   2. Ethane minimum purity 99.1%.
   3. Water was distilled and deaerated.

Estimated Errors:
   Solubility: δx/x = ± 5% (Authors)
δy/y = ± 2% - 5%
   Temperature: δT/K = ± 0.1
   Pressure: δP/P = ± 0.2%

References:
   1. Wehe, A.H.; McKetta, J.J., J. Chem. Eng. Data 1961, 6, 167.
   2. Wehe, A.H.; McKetta, J.J., Anal. Chem. 1961, 33, 291.