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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Ethene with 1, 3-Dioxolan-2-one, 4-methyl- (Propylene carbonate)
Components:
(1) Ethane, 1, 2-Dichloro- (Ethylenedichloride); C2H4Cl2; [107-06-2]
NIST Chemistry WebBook
for detail
(2) 1, 3-Dioxolan-2-one, 4-methyl- (Propylene carbonate); C4H6O3; [108-32-7]
NIST Chemistry WebBook
for detail
Original Measurements:
Shakhova, S.F.; Zubchenko, Yu P.; Rezina, O.A., Khim. Prom., 1973, 49, 271-2.
Variables:
Temperature = 298.15 K to 343.15 K
Pressure = 0.52 to 4.22 MPa
Prepared By:
C.L. Young
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
Table 1. Mole fraction of ethene in liquid,
x
C
2
H
4
T/K
Pressure [MPa]
Mole Fraction (x
1
)
x
1
Note
Volume
Volume Note
298.15
0.517
0.0216
Liquid
5.8
+
298.15
0.719
0.0310
Liquid
8.4
+
298.15
0.861
0.0356
Liquid
9.7
+
298.15
0.983
0.0409
Liquid
11.2
+
298.15
2.077
0.0843
Liquid
24.2
+
298.15
2.695
0.1034
Liquid
30.3
+
298.15
3.830
0.1423
Liquid
43.6
+
323.15
0.557
0.0196
Liquid
5.25
+
323.15
0.811
0.0250
Liquid
6.75
+
323.15
1.246
0.0384
Liquid
10.5
+
323.15
1.600
0.0492
Liquid
13.6
+
323.15
2.209
0.0667
Liquid
18.8
+
323.15
3.040
0.0900
Liquid
26.0
+
323.15
4.021
0.1124
Liquid
33.3
+
323.15
4.361
0.1246
Liquid
37.4
+
343.15
0.661
0.0175
Liquid
4.68
+
343.15
1.021
0.0258
Liquid
6.97
+
343.15
1.031
0.0270
Liquid
7.30
+
343.15
1.401
0.0345
Liquid
9.40
+
343.15
2.471
0.0641
Liquid
18.0
+
343.15
3.441
0.0843
Liquid
24.2
+
343.15
4.171
0.1031
Liquid
30.2
+
343.15
4.221
0.1034
Liquid
30.3
+
Notes:
+
quoted in original paper,k appears to be volume of gas at
T
/K = 273.15 and
P
= 1 atmosphere adsorbed by unit volume or liquid at room temperature.
Method/Apparatus/Procedure:
Mixture stirred by ball in rocking sutoclave. Samples of liquid analysed by volumetric method. Details in Ref. 1.
Henry's constants were listed as follows:
t/C H/atm mole fraction
1
25 235
50 298
70 333
Source and Purity of Materials:
1. Purity 99.97 mole per cent.
2. Distilled, no other details given.
Estimated Errors:
Solubility: δ
x
C
2
H
4
= ± 5% (estimated by compiler)
Temperature: δ
T
/K = ± 0.1 (estimated by compiler)
Pressure: δ
p
/MPa = ± 0.01 (estimated by compiler)
References:
1. Shakhova, S. F.; Zubchenko, Yu. P.; Kaplan, L. K., Khim. Prom. 1973, 5, 108.