IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ethene with 1, 3-Dioxolan-2-one, 4-methyl- (Propylene carbonate)

Components:
   (1) Ethane, 1, 2-Dichloro- (Ethylenedichloride); C2H4Cl2; [107-06-2]  NIST Chemistry WebBook for detail
   (2) 1, 3-Dioxolan-2-one, 4-methyl- (Propylene carbonate); C4H6O3; [108-32-7]  NIST Chemistry WebBook for detail

Original Measurements:
   Shakhova, S.F.; Zubchenko, Yu P.; Rezina, O.A., Khim. Prom., 1973, 49, 271-2.

Variables:
   Temperature = 298.15 K to 343.15 K
   Pressure = 298.15 K to 343.15 K

Prepared By:
   C.L. Young

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
  
Table 1. Mole fraction of ethene in liquid, xC2H4
T/KPressure [MPa]Mole Fraction (x1)x1 NoteVolumeVolume Note
298.150.5170.0216Liquid5.8+
298.150.7190.0310Liquid8.4+
298.150.8610.0356Liquid9.7+
298.150.9830.0409Liquid11.2+
298.152.0770.0843Liquid24.2+
298.152.6950.1034Liquid30.3+
298.153.8300.1423Liquid43.6+
323.150.5570.0196Liquid5.25+
323.150.8110.0250Liquid6.75+
323.151.2460.0384Liquid10.5+
323.151.6000.0492Liquid13.6+
323.152.2090.0667Liquid18.8+
323.153.0400.0900Liquid26.0+
323.154.0210.1124Liquid33.3+
323.154.3610.1246Liquid37.4+
343.150.6610.0175Liquid4.68+
343.151.0210.0258Liquid6.97+
343.151.0310.0270Liquid7.30+
343.151.4010.0345Liquid9.40+
343.152.4710.0641Liquid18.0+
343.153.4410.0843Liquid24.2+
343.154.1710.1031Liquid30.2+
343.154.2210.1034Liquid30.3+
Notes:
   +  quoted in original paper,k appears to be volume of gas at T/K = 273.15 and P = 1 atmosphere adsorbed by unit volume or liquid at room temperature.

Method/Apparatus/Procedure:
   Mixture stirred by ball in rocking sutoclave. Samples of liquid analysed by volumetric method. Details in Ref. 1.

Henry's constants were listed as follows:

   t/C   H/atm mole fraction–1
   25            235
   50            298
   70            333

Source and Purity of Materials:
   1. Purity 99.97 mole per cent.
   2. Distilled, no other details given.

Estimated Errors:
   Solubility: δxC2H4 = ± 5% (estimated by compiler)
   Temperature: δT/K = ± 0.1 (estimated by compiler)
   Pressure: δp/MPa = ± 0.01 (estimated by compiler)

References:
   1. Shakhova, S. F.; Zubchenko, Yu. P.; Kaplan, L. K., Khim. Prom. 1973, 5, 108.