IUPAC-NIST Solubility Database
NIST Standard Reference Database 106


Glass Ball as Bullet Solubility System: Ethene with 2-Butanone (methyl ethylketone)

Components:
   (1) Ethene; C2H4; [74-85-1]  NIST Chemistry WebBook for detail
   (2) 2-Butanone (methyl ethylketone); C4H8O; [78-93-3]  NIST Chemistry WebBook for detail

Original Measurements:
   Shenderei, E.R.; Zel ' venskii, Ya.D.; Ivanovskii, F.P., Zhur. Fiz. Khim. 1962, 36, 801-808.

Variables:
   Temperature = 223.05 K to 248.15 K
   Pressure = 223.05 K to 248.15 K

Prepared By:
   C.L. Young

Experimental Data:   (Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
  
T/KPressure [bar]Mole Fraction (x1)SolubilitySolubility Note
248.153.00.095032.32+
248.155.10.162259.52+
248.1510.10.3349155.11+
248.1512.20.4169220.24+
248.1515.20.5381352.56+
248.1518.20.6070708.29+
238.153.00.118041.02+
238.155.10.200076.08+
238.1510.10.4477249.62+
238.1512.20.5685404.49+
238.1515.20.83001503.32+
223.053.00.162059.52+
223.055.10.2787118.56+
223.0510.10.6830663.42+
Notes:
   +  cm3g–1 at P = 101.325 kPa

Method/Apparatus/Procedure:
   Glass equilibrium cell fitted with magnetic stirrer. Pressure measured with Bourdon gauge. Samples of liquid analysed by stripping out ethene. Details in Ref. 1.

Source and Purity of Materials:
   1. Prepared from ethanol by dehydration and purified by absorption in cuprous chloride under pressure.
   2. Distilled.

Estimated Errors:
   Solubility: δxC2H4 = ± 2% (estimated by compiler)
   Temperature: δT/K = ± 0.1 (estimated by compiler)
   Pressure: δp/bar = ± 0.3 (estimated by compiler)

References:
   1. Shenderei, E.R.; Zelvenskii, Ya.D.; Ivanovskii, F.P., Khim. Prom. 1960, 370.