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IUPAC-NIST Solubility Database
NIST Standard Reference Database 106
Solubility System:
Ethene with 2-Butanone (methyl ethylketone)
Components:
(1) Ethene; C2H4; [74-85-1]
NIST Chemistry WebBook
for detail
(2) 2-Butanone (methyl ethylketone); C4H8O; [78-93-3]
NIST Chemistry WebBook
for detail
Original Measurements:
Shenderei, E.R.; Zel ' venskii, Ya.D.; Ivanovskii, F.P., Zhur. Fiz. Khim. 1962, 36, 801-808.
Variables:
Temperature = 223.05 K to 248.15 K
Pressure = 223.05 K to 248.15 K
Prepared By:
C.L. Young
Experimental Data:
(Subscripts 1,2,3, ..., in column headings refer to components 1,2,3, ...)
T/K
Pressure [bar]
Mole Fraction (x
1
)
Solubility
Solubility Note
248.15
3.0
0.0950
32.32
+
248.15
5.1
0.1622
59.52
+
248.15
10.1
0.3349
155.11
+
248.15
12.2
0.4169
220.24
+
248.15
15.2
0.5381
352.56
+
248.15
18.2
0.6070
708.29
+
238.15
3.0
0.1180
41.02
+
238.15
5.1
0.2000
76.08
+
238.15
10.1
0.4477
249.62
+
238.15
12.2
0.5685
404.49
+
238.15
15.2
0.8300
1503.32
+
223.05
3.0
0.1620
59.52
+
223.05
5.1
0.2787
118.56
+
223.05
10.1
0.6830
663.42
+
Notes:
+
cm
3
g
1
at
P
= 101.325 kPa
Method/Apparatus/Procedure:
Glass equilibrium cell fitted with magnetic stirrer. Pressure measured with Bourdon gauge. Samples of liquid analysed by stripping out ethene. Details in Ref. 1.
Source and Purity of Materials:
1. Prepared from ethanol by dehydration and purified by absorption in cuprous chloride under pressure.
2. Distilled.
Estimated Errors:
Solubility: δ
x
C
2
H
4
= ± 2% (estimated by compiler)
Temperature: δ
T
/K = ± 0.1 (estimated by compiler)
Pressure: δ
p
/bar = ± 0.3 (estimated by compiler)
References:
1. Shenderei, E.R.; Zelvenskii, Ya.D.; Ivanovskii, F.P., Khim. Prom. 1960, 370.